التفاصيل البيبلوغرافية
| العنوان: |
Generation of Heteroaryl-Substituted Sulfonyl Compounds from Sulfur Dioxide via Remote Heteroaryl ipso -Migration |
| المؤلفون: |
Man Yang (221504), Xiaotong Chang (11551455), Shengqing Ye (2067415), Qiuping Ding (343405), Jie Wu (10038) |
| سنة النشر: |
2021 |
| المجموعة: |
Smithsonian Institution: Digital Repository |
| مصطلحات موضوعية: |
Biochemistry, Medicine, Genetics, Evolutionary Biology, Developmental Biology, Environmental Sciences not elsewhere classified, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, various functional groups, substituted tertiary alcohols, substituted sulfonyl compounds, broad substrate scope, sulfonyl radical addition, 2 , radical process, ipso <, unactivated alkene, tolerated well, sulfur dioxide, reaction undergoes, mild conditions, free three, dabco ·(, component reaction, aryldiazonium tetrafluoroborates, >- migration |
| الوصف: |
The generation of heteroaryl-substituted sulfonyl compounds via a catalyst-, base-, and additive-free three-component reaction of heteroaryl-substituted tertiary alcohols, aryldiazonium tetrafluoroborates, and DABCO·(SO 2 ) 2 under mild conditions is developed. Various functional groups are tolerated well in this transformation, and a broad substrate scope is demonstrated. A preliminary mechanistic investigation shows that this reaction undergoes a radical process, including the insertion of sulfur dioxide, sulfonyl radical addition to unactivated alkene, and remote heteroaryl ipso -migration. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| Relation: |
https://figshare.com/articles/journal_contribution/Generation_of_Heteroaryl-Substituted_Sulfonyl_Compounds_from_Sulfur_Dioxide_via_Remote_Heteroaryl_i_ipso_i_-Migration/16795092 |
| DOI: |
10.1021/acs.joc.1c01778.s001 |
| الاتاحة: |
https://doi.org/10.1021/acs.joc.1c01778.s001 |
| Rights: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.D7C7CFE2 |
| قاعدة البيانات: |
BASE |