التفاصيل البيبلوغرافية
| العنوان: |
An Examination of the Electron Densities in a Series of Tripodal Cobalt Complexes Bridged by Magnesium, Calcium, Strontium, and Barium † |
| المؤلفون: |
John Bacsa, Lillian G. Ramírez-Palma, Fernando Cortés-Guzmán, Christian M. Wallen, Christopher C. Scarborough |
| المصدر: |
Crystals; Volume 8; Issue 6; Pages: 234 |
| بيانات النشر: |
Multidisciplinary Digital Publishing Institute |
| سنة النشر: |
2018 |
| المجموعة: |
MDPI Open Access Publishing |
| مصطلحات موضوعية: |
quantum theory of atoms in molecules (QTAIM), alkaline earth metals, theoretical electron densities |
| الوصف: |
X-ray crystallographic and theoretical charge-density data for a series of compounds—[(Co(Ts3tren))M(Co(Ts3tren))], (M = Mg, Ca, Sr and Ba)—were examined. The crystal structures were isostructural, and the alkaline-earth-metal ions had the same six-coordinate environment oxygen donor atoms which was octahedral despite the large variation in their ionic radii. The isomorphism of these molecules was surprising, and a theoretical examination of their electronic structures, with various metal ions along the series, provided detailed insight into their stabilities. The theoretical and experimental data were consistent and agreed well. The local properties of the Co(II) ion and its donor atoms were relatively independent of the alkaline earth metals. |
| نوع الوثيقة: |
text |
| وصف الملف: |
application/pdf |
| اللغة: |
English |
| Relation: |
https://dx.doi.org/10.3390/cryst8060234 |
| DOI: |
10.3390/cryst8060234 |
| الاتاحة: |
https://doi.org/10.3390/cryst8060234 |
| Rights: |
https://creativecommons.org/licenses/by/4.0/ |
| رقم الانضمام: |
edsbas.D5416DEC |
| قاعدة البيانات: |
BASE |