Academic Journal
Homo‐oligohistidines ; Part II. Preferred conformations in solution of a series of N(α)‐t‐butoxycarbonyl, N(π)‐benzyloxymethyl‐homo‐oligo‐L‐histidine methyl esters, from the dipeptide to the heptapeptide
| العنوان: | Homo‐oligohistidines ; Part II. Preferred conformations in solution of a series of N(α)‐t‐butoxycarbonyl, N(π)‐benzyloxymethyl‐homo‐oligo‐L‐histidine methyl esters, from the dipeptide to the heptapeptide |
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| المؤلفون: | Bonora, G.M., Toniolo, C., Jones, J.H., Rajasekharan, K.N. |
| المصدر: | International Journal of Peptide and Protein Research ; volume 27, issue 1, page 1-6 ; ISSN 0367-8377 |
| بيانات النشر: | Wiley |
| سنة النشر: | 1986 |
| المجموعة: | Wiley Online Library (Open Access Articles via Crossref) |
| الوصف: | Conformational studies (CD, i.r., 1 H n.m.r.) are reported for a series of N (α)‐t‐butoxycarbonyl, N (π)‐benzyloxymethyl‐homo‐oligo‐L‐histidine methyl esters ranging from the dipeptide to the heptapeptide. In chloroform at high dilution the extent and stability of intramolecularly hydrogen‐bonded folded forms were assessed as a function of chain length. In this low‐polarity solvent at high concentration the heptapeptide adopts a well developed intermolecularly hydrogen‐bonded β‐structure. In polar solvents such as 1,1,1,3,3,3,‐hexafluoro‐propan‐2‐ol and dimethylsulphoxide, unordered solvated forms were found to predominate. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| DOI: | 10.1111/j.1399-3011.1986.tb02759.x |
| الاتاحة: | http://dx.doi.org/10.1111/j.1399-3011.1986.tb02759.x https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1111%2Fj.1399-3011.1986.tb02759.x https://onlinelibrary.wiley.com/doi/pdf/10.1111/j.1399-3011.1986.tb02759.x |
| Rights: | http://onlinelibrary.wiley.com/termsAndConditions#vor |
| رقم الانضمام: | edsbas.D513BE78 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1111/j.1399-3011.1986.tb02759.x |
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