Academic Journal
Water-Mediated ElectroHydrogenation of CO2at Near-Equilibrium Potential by Carbon Nanotubes/Cerium Dioxide Nanohybrids
| العنوان: | Water-Mediated ElectroHydrogenation of CO2at Near-Equilibrium Potential by Carbon Nanotubes/Cerium Dioxide Nanohybrids |
|---|---|
| المؤلفون: | Valenti G., Melchionna M., Montini T., Boni A., Nasi L., Fonda E., Criado A., Zitolo A., Voci S., Bertoni G., Bonchio M., Fornasiero P., Paolucci F., Prato M. |
| المساهمون: | Valenti G., Melchionna M., Montini T., Boni A., Nasi L., Fonda E., Criado A., Zitolo A., Voci S., Bertoni G., Bonchio M., Fornasiero P., Paolucci F., Prato M. |
| سنة النشر: | 2020 |
| المجموعة: | IRIS Università degli Studi di Bologna (CRIS - Current Research Information System) |
| مصطلحات موضوعية: | carbon dioxide reduction, carbon nanotube, cerium oxide, electrocatalytic hydrogenation, metal oxide electrocatalysts |
| الوصف: | The combination of multiwalled carbon nanotubes (MWCNTs) with undoped CeO2 nanoparticles (NPs) is effective for the direct electrocatalytic reduction of CO2 to formic acid (FA) at acidic pH (0.1 M HNO3), at overpotential as low as η = -0.02 V (vs RHE) with Faradic efficiency (FE) up to 65%. Ex situ and operando evidence identifies nonstoichiometric Ce4+/3+O2-x reduced sites as essential for the selective CO2 reduction reaction (CO2RR). The MWCNT-mediated electrochemical reduction of the CeO2 NPs offers a definite advantage with respect to the generally adopted thermochemical cycles (800-1500 °C) or deep hydrogenation pretreatments, thus presenting an interesting perspective for the engineering of CeO2 electrocatalysts. |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | ELETTRONICO |
| اللغة: | English |
| Relation: | info:eu-repo/semantics/altIdentifier/wos/WOS:000576676900045; volume:3; issue:9; firstpage:8509; lastpage:8518; numberofpages:10; journal:ACS APPLIED ENERGY MATERIALS; https://hdl.handle.net/11585/778700; info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-85094838990 |
| DOI: | 10.1021/acsaem.0c01145 |
| الاتاحة: | https://hdl.handle.net/11585/778700 https://doi.org/10.1021/acsaem.0c01145 |
| Rights: | info:eu-repo/semantics/openAccess |
| رقم الانضمام: | edsbas.D2D97E6E |
| قاعدة البيانات: | BASE |
| DOI: | 10.1021/acsaem.0c01145 |
|---|