التفاصيل البيبلوغرافية
| العنوان: |
Carburized In 2 O 3 Nanorods Endow CO 2 Electroreduction to Formate at 1 A cm –2 |
| المؤلفون: |
Wenhang Wang (12085522), Xiaoshan Wang (223669), Zhengguang Ma (12835688), Yang Wang (5921), Zhongxue Yang (6560006), Jiexin Zhu (4249453), Lei Lv (169816), Hui Ning (1893130), Noritatsu Tsubaki (1266459), Mingbo Wu (1465525) |
| سنة النشر: |
2022 |
| مصطلحات موضوعية: |
Biophysics, Inorganic Chemistry, Space Science, Environmental Sciences not elsewhere classified, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, Physical Sciences not elsewhere classified, wide potential range, enhanced raman spectroscopy, double high index, complete reaction path, 3 , producing formate efficiently, nanorods endow co, high faradaic efficiency, carbon dioxide electroreduction, 2 , faradaic efficiency, situ investigated, negative charges, great challenge, flow cell, electronic structure, current density, 500 mv |
| الوصف: |
The double high index of current density and Faradaic efficiency in carbon dioxide electroreduction is a great challenge. Herein, we synthesized carburized indium oxide nanorods (In 2 O 3 -C) by pyrolysis of the metal–organic framework (MOF) precursor [MIL-68 (In)]. The electronic structure of In was regulated, and the localization of negative charges was increased on the surface of the In 2 O 3 -C catalyst, resulting in a high Faradaic efficiency of 97.2% at −1.0 V vs RHE and above 90% in a wide potential range of 500 mV. Furthermore, it reached a current density of −1.0 A·cm –2 in the flow cell for producing formate efficiently. The complete reaction path from CO 2 to formate on In 2 O 3 -C was in situ investigated by attenuated total reflection surface-enhanced infrared adsorption spectroscopy and 2D/3D surface-enhanced Raman spectroscopy. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| Relation: |
https://figshare.com/articles/journal_contribution/Carburized_In_sub_2_sub_O_sub_3_sub_Nanorods_Endow_CO_sub_2_sub_Electroreduction_to_Formate_at_1_A_cm_sup_2_sup_/21782283 |
| DOI: |
10.1021/acscatal.2c05006.s001 |
| الاتاحة: |
https://doi.org/10.1021/acscatal.2c05006.s001 |
| Rights: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.D25B959F |
| قاعدة البيانات: |
BASE |