التفاصيل البيبلوغرافية
| العنوان: |
A Sandwich-Structure Composite Polymer Electrolyte Based on Poly(vinyl alcohol)/Poly(4-lithium styrene sulfonic acid) for High-Voltage Lithium Batteries |
| المؤلفون: |
Hoai Khang Tran (9595669), Lakshmipriya Musuvadhi Babulal (9952201), Yi-Shiuan Wu (9595672), Tai-Feng Hung (1586473), Wen-Chen Chien (9595675), She-Huang Wu (3032658), Rajan Jose (1544974), Shingjiang Jessie Lue (8065922), Chun-Chen Yang (4479739) |
| سنة النشر: |
2021 |
| المجموعة: |
Smithsonian Institution: Digital Repository |
| مصطلحات موضوعية: |
Biophysics, Biochemistry, Medicine, Microbiology, Neuroscience, Biotechnology, Immunology, Mental Health, Hematology, Infectious Diseases, Virology, Chemical Sciences not elsewhere classified, stability, electrolyte, retention, PVDF-HFP-LiTFSI skin layers, LLZO, sulfonic, CPE, CR 2032 coin cell, Al-doped Li 7 La 3 Zr 2 O 12, sandwich-CPE, High-Voltage Lithium Batteries High., lithium dendrite growth, acid, electrode, conductivity, ASSLMB, 18.1 mA h, poly |
| الوصف: |
High-performance all-solid-state lithium-metal batteries (ASSLMBs) require solid electrolytes displaying high electrochemical stability, high ion conductivity, a high lithium transference number, excellent compatibility with the electrodes, and the ability to work at room temperature. In this study, we used a solution-casting technique to prepare a flexible composite polymer electrolyte (CPE) having a high lithium transference number and applied it within ASSLMBs. The CPE comprised a poly(vinyl alcohol) (PVA)/poly(4-lithium styrene sulfonic acid) (PLSS) blend with an Al-doped Li 7 La 3 Zr 2 O 12 (LLZO) filler sandwiched on both sides by poly(vinylidene fluoride- co -hexafluoropropylene) (PVDF-HFP)–lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) skin layers. The PVDF-HFP-LiTFSI skin layers not only lowered the interfacial resistance between the electrodes and the sandwich-CPE electrolyte but also suppressed lithium dendrite growth. The sandwich-CPE membrane exhibited high ionic conductivity (3.82 × 10 –4 S cm –1 ) and a high lithium transference number (0.776) at room temperature. A CR2032 coin cell having the structure Li/sandwich-CPE/LMO@T-LNCM811 delivered excellent rate performance and cycle stability (discharge capacity of 130.55 mA h g –1 with 85.63% capacity retention after 100 cycles at a rate of 0.5C at room temperature). A pouch cell having the structure Li/sandwich-CPE/LMO@T-LNCM811 achieved a discharge capacity of 18.1 mA h with a capacity retention of 90.46% after 30 cycles at 0.2C at room temperature. This strategy for fabricating sandwich-CPE structures has potential for application in the preparation of high-voltage cathodes for ASSLMBs. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| Relation: |
https://figshare.com/articles/journal_contribution/A_Sandwich-Structure_Composite_Polymer_Electrolyte_Based_on_Poly_vinyl_alcohol_Poly_4-lithium_styrene_sulfonic_acid_for_High-Voltage_Lithium_Batteries/15070852 |
| DOI: |
10.1021/acsaem.1c01333.s001 |
| الاتاحة: |
https://doi.org/10.1021/acsaem.1c01333.s001 |
| Rights: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.D162B520 |
| قاعدة البيانات: |
BASE |