التفاصيل البيبلوغرافية
| العنوان: |
Potassium Decahydrido- closo -Decaborane Urea Complex as a Potential Solid-State Electrolyte for Potassium Metal Batteries |
| المؤلفون: |
Zhiwei Lu, Pengtao Qiu, Jia-Xin Kang, Xinwei Chen, Guoguo Zhang, Yichun Zhang, Xuenian Chen |
| سنة النشر: |
2024 |
| المجموعة: |
Smithsonian Institution: Figshare |
| مصطلحات موضوعية: |
Biophysics, Biochemistry, Biotechnology, Hematology, Infectious Diseases, Astronomical and Space Sciences not elsewhere classified, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, Physical Sciences not elsewhere classified, scale energy storage, remarkable interface compatibility, potassium decahydrido -<, one possible reason, 7 × 10, 3 × 10, 80 ° c, 25 ° c, considered promising candidates, potassium metal batteries, k metal electrodes, 10 , ion solid electrolytes, ion conductors reported, 2 , c <, promising electrolyte, ion conductivity, ion conductivities, closo <, wide availability |
| الوصف: |
All-solid-state potassium metal batteries have been considered promising candidates for large-scale energy storage because of abundance and wide availability of K resources, elimination of flammable liquid organic electrolytes, and incorporation of high-capacity K metal anode. However, unideal K-ion conductivities of most reported K-ion solid electrolytes have restricted the development of these batteries. Herein, a novel K 2 B 10 H 10 ·CO(NH 2 ) 2 complex is reported, forming by incorporating urea into K 2 B 10 H 10 , to achieve an enhanced K-ion conductivity. The crystal structure of K 2 B 10 H 10 ·CO(NH 2 ) 2 was determined as a monoclinic lattice with the space group of C 2/ c (No. 15). K 2 B 10 H 10 ·CO(NH 2 ) 2 delivers an ionic conductivity of 2.7 × 10 –8 S cm –1 at 25 °C, and reaching 1.3 × 10 –4 S cm –1 at 80 °C, which is about 4 orders of magnitude higher than that of K 2 B 10 H 10 . One possible reason is the anion expansion in size due to the presence of dihydrogen bonds in K 2 B 10 H 10 ·CO(NH 2 ) 2 , resulting in an increase in the K–H bond distance and the electrostatic potential, thereby enhancing the mobility of K + . The K-ion conductivity is also higher than those of most hydridoborate-based K-ion conductors reported. Besides, K 2 B 10 H 10 ·CO(NH 2 ) 2 reveals a wide electrochemical stability window and remarkable interface compatibility with K metal electrodes, suggesting a promising electrolyte for all-solid-state K metal batteries. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| Relation: |
https://figshare.com/articles/journal_contribution/Potassium_Decahydrido-_i_closo_i_-Decaborane_Urea_Complex_as_a_Potential_Solid-State_Electrolyte_for_Potassium_Metal_Batteries/25257097 |
| DOI: |
10.1021/acsami.3c17570.s001 |
| الاتاحة: |
https://doi.org/10.1021/acsami.3c17570.s001 |
| Rights: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.D148657 |
| قاعدة البيانات: |
BASE |