Academic Journal
Phase Behaviour, Interactions, and Structural Studies of (Amines+Ionic Liquids) Binary Mixtures
| العنوان: | Phase Behaviour, Interactions, and Structural Studies of (Amines+Ionic Liquids) Binary Mixtures |
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| المؤلفون: | Jacquemin, J., Bendová, M. (Magdalena), Sedláková, Z. (Zuzana), Holbrey, J.D., Mullan, C.L., Youngs, T.G.A., Pison, L., Wagner, Z. (Zdeněk), Aim, K. (Karel), Costa Gomes, M.F., Hardacre, Ch. |
| سنة النشر: | 2012 |
| المجموعة: | The Czech Academy of Sciences: Publication Activity (ASEP) / Akademie věd ČR - Publikační činnost |
| مصطلحات موضوعية: | amines, interactions, ionic liquids |
| الوصف: | We present a study on the phase equilibrium behaviour of binary mixtures containing two 1-alkyl-3-methylimidazolium bis{(trifluoromethyl)sulfonyl}imide-based ionic liquids, [Cnmim][NTf2] (n = 2 and 4), mixed with diethylamine or triethylamine as a function of temperature and composition using different experimental techniques. Their phase behaviours have been then correlated and predicted by using Flory-Huggins equations and UNIQUAC method. The potential of the COSMO-RS methodology to predict the phase equilibria was also tested for the studied binary systems. The liquid state structure of the binary mixture [C2mim][NTf2] + diethylamine has also been investigated by molecular dynamics simulation and neutron diffraction. Finally, the absorption of gaseous ethane by the ([C2mim][NTf2] + diethylamine) binary mixture was determined and compared with those observed in the pure solvents. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| تدمد: | 1439-4235 1439-7641 |
| Relation: | urn:pissn: 1439-4235; urn:eissn: 1439-7641; http://hdl.handle.net/11104/0209269 |
| DOI: | 10.1002/cphc.201100952 |
| الاتاحة: | https://doi.org/10.1002/cphc.201100952 http://hdl.handle.net/11104/0209269 |
| Rights: | info:eu-repo/semantics/openAccess |
| رقم الانضمام: | edsbas.D0188BCB |
| قاعدة البيانات: | BASE |
| تدمد: | 14394235 14397641 |
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| DOI: | 10.1002/cphc.201100952 |