التفاصيل البيبلوغرافية
| العنوان: |
One-Step Electropolymerization of a Dicyanobenzene-Carbazole-Imidazole Dye to Prepare Photoactive Redox Polymer Films |
| المؤلفون: |
Jinkun Liu, Octavio Martinez Perez, Dominic Lavergne, Loorthuraja Rasu, Elizabeth Murphy, Andy Galvez-Rodriguez, Steven H. Bergens |
| المصدر: |
Polymers; Volume 15; Issue 16; Pages: 3340 |
| بيانات النشر: |
Multidisciplinary Digital Publishing Institute |
| سنة النشر: |
2023 |
| المجموعة: |
MDPI Open Access Publishing |
| مصطلحات موضوعية: |
4CzIPN, 3CzImIPN, photoredox-POP, photochemistry, polymerization |
| الوصف: |
To the best of our knowledge, this study reports the first direct electropolymerization of a dicyanobenzene-carbazole dye functionalized with an imidazole group to prepare redox- and photoactive porous organic polymer (POP) films in controlled amounts. The POP films were grown on indium-doped tin oxide (ITO) and carbon surfaces using a new monomer, 1-imidazole-2,4,6-tri(carbazol-9-yl)-3,5-dicyanobenzene (1, 3CzImIPN), through a simple one-step process. The structure and activities of the POP films were investigated as photoelectrodes for electrooxidations, as heterogeneous photocatalysts for photosynthetic olefin isomerizations, and for solid-state photoluminescence behavior tunable by lithium-ion concentrations in solution. The results demonstrate that the photoredox-POPs can be used as efficient photocatalysts, and they have potential applications in sensing. |
| نوع الوثيقة: |
text |
| وصف الملف: |
application/pdf |
| اللغة: |
English |
| Relation: |
Polymer Chemistry; https://dx.doi.org/10.3390/polym15163340 |
| DOI: |
10.3390/polym15163340 |
| الاتاحة: |
https://doi.org/10.3390/polym15163340 |
| Rights: |
https://creativecommons.org/licenses/by/4.0/ |
| رقم الانضمام: |
edsbas.CFDE68CA |
| قاعدة البيانات: |
BASE |