Academic Journal
Thiocarbamoyl Fluoride Synthesis by Deconstructive Diversification of Arylated Tetrahydroisoquinolines
| العنوان: | Thiocarbamoyl Fluoride Synthesis by Deconstructive Diversification of Arylated Tetrahydroisoquinolines |
|---|---|
| المؤلفون: | Wentao Xu (187610), Fang Liu (13271), Jiajun Li (1410187), Muzi Li (698159), Jin Xie (690890), Chengjian Zhu (1492816) |
| سنة النشر: | 2021 |
| المجموعة: | Smithsonian Institution: Digital Repository |
| مصطلحات موضوعية: | Biophysics, Biochemistry, Medicine, Molecular Biology, Biotechnology, Evolutionary Biology, Ecology, Developmental Biology, Marine Biology, Chemical Sciences not elsewhere classified, thiocarbamoyl fluorides, Thiocarbamoyl Fluoride Synthesis, access, amines, Arylated Tetrahydroisoquinolines De. |
| الوصف: | Deconstructive functionalization of cyclic amines can provide access to chemicals with diverse skeletons. We report the conversion of tertiary amines to thiocarbamoyl fluorides, a reaction enabled by photoredox catalysis and tolerating different functional groups while avoiding strong oxidants. A one-pot synthetic method from tertiary amines and AgF has been developed to get access to trifluoromethylamines. The synthesized thiocarbamoyl fluorides can be further transferred into esters. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | unknown |
| Relation: | https://figshare.com/articles/journal_contribution/Thiocarbamoyl_Fluoride_Synthesis_by_Deconstructive_Diversification_of_Arylated_Tetrahydroisoquinolines/15078893 |
| DOI: | 10.1021/acs.joc.1c01468.s001 |
| الاتاحة: | https://doi.org/10.1021/acs.joc.1c01468.s001 |
| Rights: | CC BY-NC 4.0 |
| رقم الانضمام: | edsbas.CF64E255 |
| قاعدة البيانات: | BASE |
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