التفاصيل البيبلوغرافية
| العنوان: |
Thiocarbamoyl Fluoride Synthesis by Deconstructive Diversification of Arylated Tetrahydroisoquinolines |
| المؤلفون: |
Wentao Xu (187610), Fang Liu (13271), Jiajun Li (1410187), Muzi Li (698159), Jin Xie (690890), Chengjian Zhu (1492816) |
| سنة النشر: |
2021 |
| المجموعة: |
Smithsonian Institution: Digital Repository |
| مصطلحات موضوعية: |
Biophysics, Biochemistry, Medicine, Molecular Biology, Biotechnology, Evolutionary Biology, Ecology, Developmental Biology, Marine Biology, Chemical Sciences not elsewhere classified, thiocarbamoyl fluorides, Thiocarbamoyl Fluoride Synthesis, access, amines, Arylated Tetrahydroisoquinolines De. |
| الوصف: |
Deconstructive functionalization of cyclic amines can provide access to chemicals with diverse skeletons. We report the conversion of tertiary amines to thiocarbamoyl fluorides, a reaction enabled by photoredox catalysis and tolerating different functional groups while avoiding strong oxidants. A one-pot synthetic method from tertiary amines and AgF has been developed to get access to trifluoromethylamines. The synthesized thiocarbamoyl fluorides can be further transferred into esters. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| Relation: |
https://figshare.com/articles/journal_contribution/Thiocarbamoyl_Fluoride_Synthesis_by_Deconstructive_Diversification_of_Arylated_Tetrahydroisoquinolines/15078893 |
| DOI: |
10.1021/acs.joc.1c01468.s001 |
| الاتاحة: |
https://doi.org/10.1021/acs.joc.1c01468.s001 |
| Rights: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.CF64E255 |
| قاعدة البيانات: |
BASE |