Academic Journal
General synthesis of 2D rare-earth oxide single crystals with tailorable facets
| العنوان: | General synthesis of 2D rare-earth oxide single crystals with tailorable facets |
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| المؤلفون: | Li, Linyang, Lu, Fangyun, Xiong, Wenqi, Ding, Yu, Lu, Yangyi, Xiao, Yao, Tong, Xin, Wang, Yao, Jia, Shuangfeng, Wang, Jianbo, Mendes, Rafael G., Rümmeli, Mark H., Yuan, Shengjun, Zeng, Mengqi, Fu, Lei |
| بيانات النشر: | Oxford University Press |
| سنة النشر: | 2022 |
| المجموعة: | DSpace VŠB-TUO (Vysoká škola báňská - Technická univerzita Ostrava / Technical University of Ostrava) |
| مصطلحات موضوعية: | 2D materials, cerium, crystal engineering, rare earth, CVD |
| الوصف: | Two-dimensional (2D) rare-earth oxides (REOs) are a large family of materials with various intriguing applications and precise facet control is essential for investigating new properties in the 2D limit. However, a bottleneck remains with regard to obtaining their 2D single crystals with specific facets because of the intrinsic non-layered structure and disparate thermodynamic stability of different facets. Herein, for the first time, we achieve the synthesis of a wide variety of high-quality 2D REO single crystals with tailorable facets via designing a hard-soft-acid-base couple for controlling the 2D nucleation of the predetermined facets and adjusting the growth mode and direction of crystals. Also, the facet-related magnetic properties of 2D REO single crystals were revealed. Our approach provides a foundation for further exploring other facet-dependent properties and various applications of 2D REO, as well as inspiration for the precise growth of other non-layered 2D materials. The synthesis of a wide variety of high-quality 2D rare-earth oxide single crystals with tailorable facets is achieved via designing a hard-soft-acid-base couple for controlling the 2D nucleation and growth of the predetermined facets. ; Web of Science ; 9 ; 5 |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| تدمد: | 2095-5138 2053-714X |
| Relation: | National Science Review; https://doi.org/10.1093/nsr/nwab153; National Science Review. 2022, vol. 9, issue 5.; http://hdl.handle.net/10084/149237; 000792252800001 |
| DOI: | 10.1093/nsr/nwab153 |
| الاتاحة: | http://hdl.handle.net/10084/149237 https://doi.org/10.1093/nsr/nwab153 |
| Rights: | Copyright © 2021, Oxford University Press ; http://creativecommons.org/licenses/by/4.0/ ; openAccess |
| رقم الانضمام: | edsbas.CDBFED89 |
| قاعدة البيانات: | BASE |
Full Text Finder | تدمد: | 20955138 2053714X |
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| DOI: | 10.1093/nsr/nwab153 |