التفاصيل البيبلوغرافية
| العنوان: |
Photoredox Polychloroalkylation/Spirocyclization of Activated Alkynes via C(sp 3 )‐H bond Cleavage |
| المؤلفون: |
Luo, Zhen‐Tao, Zhong, Long‐Jin, Zhou, Quan, Xiong, Bi‐Quan, Tang, Ke‐Wen, Liu, Yu |
| المساهمون: |
Natural Science Foundation of Hunan Province, National Natural Science Foundation of China |
| المصدر: |
European Journal of Organic Chemistry ; volume 27, issue 6 ; ISSN 1434-193X 1099-0690 |
| بيانات النشر: |
Wiley |
| سنة النشر: |
2024 |
| المجموعة: |
Wiley Online Library (Open Access Articles via Crossref) |
| الوصف: |
A novel strategy of visible‐light photoredox catalysis ipso ‐annulation of activated alkynes with polychloroalkanes for the synthesis of 3‐polychloroalkyl spiro[4,5]trienones, which used 4‐methoxybenzenediazonium tetrafluoroborate salt as a hydrogen atom transfer reagent, is described. This polychloroalkylation/ spirocyclization of alkynes offers a widely range of 3‐polychloroalkyl‐spiro[4,5]trienone derivatives in high yields with a broad substrate scope via selective C(sp 3 )‐H homolytic cleavage. The results of controlled experiments showed that this method involves a radical process. The polyhaloalkyl radical species generated from intermolecular hydrogen atom transfer (HAT) between aryl radical and polychloroalkanes. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
English |
| DOI: |
10.1002/ejoc.202301159 |
| الاتاحة: |
https://doi.org/10.1002/ejoc.202301159 |
| Rights: |
http://onlinelibrary.wiley.com/termsAndConditions#vor |
| رقم الانضمام: |
edsbas.CCA55F13 |
| قاعدة البيانات: |
BASE |