التفاصيل البيبلوغرافية
| العنوان: |
Polymerization of Biobased Farnesene in Miniemulsions by Nitroxide-Mediated Polymerization |
| المؤلفون: |
Sharmaine B. Luk (10131788), Milan Maríc (10131791) |
| سنة النشر: |
2021 |
| المجموعة: |
Smithsonian Institution: Digital Repository |
| مصطلحات موضوعية: |
Biophysics, Biochemistry, Medicine, Microbiology, Molecular Biology, Biotechnology, Virology, Chemical Sciences not elsewhere classified, Physical Sciences not elsewhere classified, Nitroxide-Mediated Polymerization B., emulsion, alkoxyamine initiators, Dispolreg 007, chain extension, isobornyl methacrylate, monomer concentration, biobased diblock copolymers, Compartmentalization effects, NHS-BB-initiated systems, nitroxide-mediated polymerization, succinimidyl-modified BlocBuilder, Successful chain extension, 30 h, unreacted macroinitiator, particle sizes, D 7 initiator, SG 1-based, Biobased Farnesene, nm, polymerization rate |
| الوصف: |
Biobased farnesene (Far) was polymerized by nitroxide-mediated polymerization in miniemulsions using two different alkoxyamine initiators, the SG1-based and succinimidyl-modified BlocBuilder (NHS-BB) and Dispolreg 007 (D7). Stable emulsions were observed after 30 h of reaction at 90 °C, where NHS-BB-initiated systems resulted in smaller particles (∼300 nm) than using D7 (∼400 nm). Successful chain extension of the poly(Far) macroinitiators (24,500–39,700 g mol –1 ) with styrene were achieved using 15 wt % surfactant relative to monomer concentration. Compartmentalization effects were not observed in these emulsions as the polymerization rate was still much slower compared to the bulk, even though Z -averaged particle sizes were around 300–400 nm. Finally, all biobased diblock copolymers were synthesized by chain-extending poly(Far) macroinitiators with isobornyl methacrylate (iBOMA), where the D7 initiator showed more effective chain extension (less unreacted macroinitiator) than NHS-BB. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| Relation: |
https://figshare.com/articles/journal_contribution/Polymerization_of_Biobased_Farnesene_in_Miniemulsions_by_Nitroxide-Mediated_Polymerization/13921637 |
| DOI: |
10.1021/acsomega.0c05992.s001 |
| الاتاحة: |
https://doi.org/10.1021/acsomega.0c05992.s001 |
| Rights: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.C94F47C4 |
| قاعدة البيانات: |
BASE |