التفاصيل البيبلوغرافية
| العنوان: |
Solar‐Assisted CO 2 Methanation via Photocatalytic Sabatier Reaction by Calcined Titanium‐based Organic Framework Supported RuO x Nanoparticles |
| المؤلفون: |
Rueda‐Navarro, Celia M., González‐Fernández, Marta, Cabrero‐Antonino, María, Dhakshinamoorthy, Amarajothi, Ferrer, Belén, Baldoví, Herme G., Navalón, Sergio |
| المصدر: |
ChemCatChem ; volume 16, issue 22 ; ISSN 1867-3880 1867-3899 |
| بيانات النشر: |
Wiley |
| سنة النشر: |
2024 |
| المجموعة: |
Wiley Online Library (Open Access Articles via Crossref) |
| الوصف: |
CO 2 reduction by sunlight under mild reaction conditions is a research area of increasing interest expected to favor decarbonization and produce fuels and chemicals in the circular economy. We hereby report on the development of a series of titanium oxide‐based solids produced by calcination of MIL‐125(Ti)‐NH 2 decorated with RuO x nanoparticles (1 wt %) material at temperatures from 350 to 650 °C and used as photocatalysts for CO 2 methanation under simulated sunlight irradiation (45 mW/cm 2 ) at <200 °C and 1.5 atm total pressure. The material synthesized at 350 °C produced the highest photoactivity of the series (4.73 mmol g −1 CH 4 at 22 h and an apparent quantum yield at 400, 500 and 750 nm of 0.76, 0.65 and 0.54 %, respectively), comparing favorably with the activities of other MOF‐based materials reported so far. Insights into the material's photocatalytic performance and a study of the possible reaction pathways during CO 2 methanation were obtained by electrochemical impedance, electron spin resonance, photoluminescence and in situ FT‐IR spectroscopies together with transient photocurrent and hydrogen temperature programed desorption measurements. The study showed the possibility of using MOF‐based materials as precursors to develop metal oxide photocatalysts with enhanced activities for solar‐driven gaseous CO 2 photomethanation. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
English |
| DOI: |
10.1002/cctc.202400991 |
| الاتاحة: |
http://dx.doi.org/10.1002/cctc.202400991 |
| Rights: |
http://creativecommons.org/licenses/by/4.0/ |
| رقم الانضمام: |
edsbas.C7BC96E4 |
| قاعدة البيانات: |
BASE |