Academic Journal
Determination of cobalt, nickel and iron at trace level in natural water samples by in-column chelation-reversed phase high-performance liquid chromatography
| العنوان: | Determination of cobalt, nickel and iron at trace level in natural water samples by in-column chelation-reversed phase high-performance liquid chromatography |
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| المؤلفون: | Elçi, Latif, Höl, AyÅŸen, Divrikli, Ãœmit |
| سنة النشر: | 2012 |
| المجموعة: | Pamukkale University Repository / Pamukkale Üniversitesi Açık Erişim Arşivi |
| مصطلحات موضوعية: | Cobalt, Iron, Mobile phase, Natural water samples, 4-(2-Pyridylazo) resorcinol, Nickel, RP-HPLC-DAD, Water, 4-(2-Pyridylazo )resorcinol, Ammonium acetate, Certified reference materials, Chelating reagent, Derivatizations, Detection limits, Full optimization, Relative standard deviations, Retention time, Reversed phase, Spiked water samples, Ni ions, Peak area, Photodiode array detectors, Trace level, Ammonium compounds, Chelation, Chromatography, Diodes, High performance liquid chromatography, Methanol, Phenols |
| الوصف: | This paper reports the utilization of 4-(2-pyridylazo) resorcinol (PAR) as a chelating reagent for in-column derivatization and the determination of trace Co, Fe, and Ni ions by reversed-phase highperformance liquid chromatography with photodiode array detector. A good separation of Co, Fe, and Ni chelates were achieved by using an Inertsil ODS-3 column and a mobile phase, consisted of methanol- THF-water mixture (50:5:45) containing ammonium acetate buffer (pH 5.0) and PAR. After full optimization, good repeatability of retention times (relative standard deviation (RSD);lt;0.05%) and peak areas (RSD;lt;1.7%) was achieved as well as a good linearity (r 2;gt;0.9991). The detection limits (S/N=3), expressed as micrograms per liter, were 0.50 (Co), 9.07 (Fe), and 2.00 (Ni). The applicability and the accuracy of the developed method were estimated by the analysis of spiked water samples and certified reference material BCR 715 wastewater-SRM. © Springer Science+Business Media B.V. 2011. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| Relation: | Environmental Monitoring and Assessment; Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı; https://hdl.handle.net/11499/8573; 184; 3469; 3479; WOS:000303679400007 |
| DOI: | 10.1007/s10661-011-2201-9 |
| الاتاحة: | https://hdl.handle.net/11499/8573 https://doi.org/10.1007/s10661-011-2201-9 |
| Rights: | none |
| رقم الانضمام: | edsbas.C6BE95CF |
| قاعدة البيانات: | BASE |
| DOI: | 10.1007/s10661-011-2201-9 |
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