Academic Journal
Controlled generation and use of CO in flow
| العنوان: | Controlled generation and use of CO in flow |
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| المؤلفون: | Hansen, Steffen V. F., Wilson, Zoe E., Ulven, Trond, Ley, Steven V. |
| المصدر: | Hansen , S V F , Wilson , Z E , Ulven , T & Ley , S V 2016 , ' Controlled generation and use of CO in flow ' , Reaction Chemistry & Engineering , vol. 1 , no. 3 , pp. 280-287 . https://doi.org/10.1039/C6RE00020G |
| سنة النشر: | 2016 |
| المجموعة: | University of Southern Denmark: Research Output / Syddansk Universitet |
| الوصف: | A method for the generation and use of carbon monoxide in flow chemistry has been developed. By using a tube-in-tube reactor, oxalyl chloride can be conveniently and safely hydrolyzed using a NaOH solution to generate CO in the outer stream, which then passes through AF-2400 semi-permeable inner tubing to enrich a reaction stream where it is consumed. The tube-in-tube reactor allows the generation of CO under conditions which would otherwise be incompatible with the reaction conditions. In this way carbonylations can be successfully performed in flow without the use of pressurized gas cylinders. Both alkoxy- and aminocarbonylation was carried out in flow, including a 320 minute continuous run, as proof of concept. |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | application/pdf |
| اللغة: | English |
| Relation: | https://portal.findresearcher.sdu.dk/da/publications/a551b9c5-a154-4c6d-95b1-3fb7f6be64e3 |
| DOI: | 10.1039/C6RE00020G |
| الاتاحة: | https://portal.findresearcher.sdu.dk/da/publications/a551b9c5-a154-4c6d-95b1-3fb7f6be64e3 https://doi.org/10.1039/C6RE00020G https://findresearcher.sdu.dk/ws/files/120047479/ReactChemEng_2016_1_280_Hansen.pdf |
| Rights: | info:eu-repo/semantics/openAccess |
| رقم الانضمام: | edsbas.C3DA74C6 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1039/C6RE00020G |
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