التفاصيل البيبلوغرافية
| العنوان: |
Enhancing Light Absorption and Prolonging Charge Separation in Carbon Quantum Dots via Cl-Doping for Visible-Light-Driven Photocharge-Transfer Reactions |
| المؤلفون: |
G. Murali (3990083), Jeevan Kumar Reddy Modigunta (11153666), Seongmin Park (1601191), Seongeun Lee (11153669), Hwiyoung Lee (11153672), Jiwon Yeon (11153675), Hyejin Kim (587175), Young Ho Park (8469570), Sung Young Park (1488805), James R. Durrant (1268991), Hyojung Cha (1688992), Tae Kyu An (1688980), Insik In (1488796) |
| سنة النشر: |
1753 |
| المجموعة: |
Smithsonian Institution: Digital Repository |
| مصطلحات موضوعية: |
Medicine, Physiology, Biotechnology, Inorganic Chemistry, Computational Biology, Space Science, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, Physical Sciences not elsewhere classified, photoexcited charge carriers, carbon quantum dots, Prolonging Charge Separation, visible-light irradiation, CQD, Enhancing Light Absorption, Visible-Light-Driven Photocharge-Tr., Cl-CQD, photoelectron transfer reactions, UV, Cl doping strategy, Ag nanoparticles, O-CQD, charge separation mechanism, absorption spectroscopy measurements |
| الوصف: |
Limited light absorption beyond the UV region and rapid photocarrier recombination are critical impediments for the improved photocatalytic performance of carbon quantum dots (CQDs) under visible-light irradiation. Herein, we demonstrate single-step microwave-assisted syntheses of O-CQDs (typical CQDs terminated by carboxylic and hydroxyl functional groups) from a sucrose precursor and Cl-doped CQDs (Cl-CQDs) from a sucralose precursor in short reaction times and without using obligatory strong acids for Cl doping. The doping of Cl into the CQDs is observed to widen the absorption range and facilitate an enhanced separation of photoexcited charge carriers, which is confirmed by the results of optical absorption, photothermal response, and pump-probe ultrafast transient absorption spectroscopy measurements of the O-CQDs and Cl-CQDs. The photoexcited charge carriers with their longer lifetimes in Cl-CQDs enabled the quick degradation of methylene blue dye, rapid conversion of Ag + ions to metallic Ag nanoparticles on the CQD surfaces, and reduction of GO to a well-dispersed rGO through the photoelectron transfer reactions under visible-light irradiation. The facile Cl doping strategy, hybridization of Ag nanoparticles or rGO to CQDs, and the elevated charge separation mechanism would open up new avenues in designing CQD-based materials for futuristic applications. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| Relation: |
https://figshare.com/articles/journal_contribution/Enhancing_Light_Absorption_and_Prolonging_Charge_Separation_in_Carbon_Quantum_Dots_i_via_i_Cl-Doping_for_Visible-Light-Driven_Photocharge-Transfer_Reactions/15016265 |
| DOI: |
10.1021/acsami.1c01879.s001 |
| الاتاحة: |
https://doi.org/10.1021/acsami.1c01879.s001 |
| Rights: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.C3975CEA |
| قاعدة البيانات: |
BASE |