Academic Journal
Two-Dimensional Mixed-Ligand Metal-Organic Framework Constructed from Bridging Bidentate V-Shaped Ligands
| العنوان: | Two-Dimensional Mixed-Ligand Metal-Organic Framework Constructed from Bridging Bidentate V-Shaped Ligands |
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| المؤلفون: | Zhong, Wen-Wu, Firuzaba, Fahimeh, Dehghani, Hanifehpour, Younes, Zeng, Xue, Feng, Yuan-Jiao, Liu, Kuan-Guan, Woo Joo, Sang, Morsali, Ali, Retailleau, Pascal |
| المساهمون: | Chongqing Medical and Pharmaceutical College, Chongqing Engineering Technology Research Center of Pharmaceutical Preparation, Shiraz University (Shiraz University), Sayyed Jamaleddin Asadabadi University (SJAU), Ningxia University, Yeungnam University (YU), Yeungnam University, Tarbiat Modares University Tehran, Institut de Chimie des Substances Naturelles (ICSN), Institut de Chimie - CNRS Chimie (INC-CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS) |
| المصدر: | ISSN: 2304-6740 ; Inorganics ; https://hal.science/hal-04080963 ; Inorganics, 2023, 11 (5), pp.184. ⟨10.3390/inorganics11050184⟩. |
| بيانات النشر: | CCSD MDPI AG |
| سنة النشر: | 2023 |
| مصطلحات موضوعية: | metal–organic framework, ditopic carboxylate ligand, polymers, porous materials, [CHIM.COOR]Chemical Sciences/Coordination chemistry, [CHIM.MATE]Chemical Sciences/Material chemistry |
| الوصف: | International audience ; A two-dimensional and bifunctional pillar-layered metal-organic framework (MOF)-with the molecular formula [Zn(cba)(bpdb)]•DMF (2DTMU-1), H 2 cba = 4,4-methylenedibenzoic acid, bpdb = 1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene-was obtained via the reaction of zinc(II) nitrate with H 2 cba as the carboxylate linker and bpdb as the N-donor pillar. 2DTMU-1 is based on a binuclear paddlewheel Zn(II) unit complexed by four bridging bidentate (dicarboxylate) V-shaped ligands, which combine to from H 2 cba; this tetragonal array, which is connected by bpdb with a bridging azine group, presents a pore size of 18 × 12 Å 2 . |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| DOI: | 10.3390/inorganics11050184 |
| الاتاحة: | https://hal.science/hal-04080963 https://hal.science/hal-04080963v1/document https://hal.science/hal-04080963v1/file/inorganics-11-00184.pdf https://doi.org/10.3390/inorganics11050184 |
| Rights: | info:eu-repo/semantics/OpenAccess |
| رقم الانضمام: | edsbas.C1CB86D0 |
| قاعدة البيانات: | BASE |
| DOI: | 10.3390/inorganics11050184 |
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