Academic Journal
A chemical kinetic mechanism for combustion and flame propagation of CH 2 F 2 /O 2 /N 2 mixtures
| العنوان: | A chemical kinetic mechanism for combustion and flame propagation of CH 2 F 2 /O 2 /N 2 mixtures |
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| المؤلفون: | Burgess, Donald R., Babushok, Valeri I., Manion, Jeffrey A. |
| المساهمون: | Office of Energy Efficiency and Renewable Energy |
| المصدر: | International Journal of Chemical Kinetics ; volume 54, issue 3, page 154-187 ; ISSN 0538-8066 1097-4601 |
| بيانات النشر: | Wiley |
| سنة النشر: | 2021 |
| المجموعة: | Wiley Online Library (Open Access Articles via Crossref) |
| الوصف: | In this work, we compiled and evaluated rate expressions for reactions relevant to the decomposition and combustion of CH 2 F 2 (difluoromethane, refrigerant R‐32) in CH 2 F 2 /O 2 /N 2 flames. The recommended values have been used in premixed flame calculations, reported elsewhere, to model experimentally derived burning velocities determined using a constant volume spherical flame method. In this work, we also provide a detailed description of the reaction pathways for decomposition and combustion of CH 2 F 2 . This work is part of a larger effort at NIST to characterize and predict the flammability of new refrigerant working fluids and their blends for consideration as replacements of current refrigerants with high global warming potentials. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| DOI: | 10.1002/kin.21549 |
| الاتاحة: | http://dx.doi.org/10.1002/kin.21549 https://onlinelibrary.wiley.com/doi/pdf/10.1002/kin.21549 https://onlinelibrary.wiley.com/doi/full-xml/10.1002/kin.21549 https://onlinelibrary.wiley.com/doi/am-pdf/10.1002/kin.21549 |
| Rights: | http://onlinelibrary.wiley.com/termsAndConditions#am ; http://onlinelibrary.wiley.com/termsAndConditions#vor |
| رقم الانضمام: | edsbas.C1037234 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1002/kin.21549 |
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