Supplementary information files for Reaction of Ph 2 C(X)(CO 2 H) (X = OH, NH 2 ) with [VO(OR) 3 ] (R = Et, nPr): structure, magnetic susceptibility and ROP capability
| العنوان: | Supplementary information files for Reaction of Ph 2 C(X)(CO 2 H) (X = OH, NH 2 ) with [VO(OR) 3 ] (R = Et, nPr): structure, magnetic susceptibility and ROP capability |
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| المؤلفون: | Mollie A Glenister, Josef Frese, Mark Elsegood, Angelos B Canaj, Euan K Brechin, Carl Redshaw |
| سنة النشر: | 2024 |
| مصطلحات موضوعية: | Inorganic chemistry, Theoretical and computational chemistry, Other chemical sciences, Inorganic & Nuclear Chemistry |
| الوصف: | (c) The Authors, CC BY-NC 3.0 Supplementary files for article Reaction of Ph 2 C(X)(CO 2 H) (X = OH, NH 2 ) with [VO(OR) 3 ] (R = Et, nPr): structure, magnetic susceptibility and ROP capability Reaction of [VO(OR)3] (R = Et, nPr) with 2,2’-diphenylglycine afforded the alkoxide-bridged dimers {[VO(OR)(mu-OR)[Ph2C(NH2)(CO2)]}2, whereas use of benzilic acid, in the presence of alkali metals, afforded 16-membered metallocycles {V8(O)4M(OR)8[Ph2C(OH)(CO2)]12} (M = <1 Na, K). For the ring systems, magnetic susceptibility data is consistent with mixed-valance vanadium with an average oxidation state of 3.5. The dimer and ring systems are capable of the ring opening polymerisation (ROP) of ε-caprolactone under N2, air, or as melts affording mostly low to medium molecular weight cyclic and linear products. |
| نوع الوثيقة: | dataset |
| اللغة: | unknown |
| Relation: | https://figshare.com/articles/dataset/Supplementary_information_files_for_Reaction_of_Ph_sub_2_sub_C_X_CO_sub_2_sub_H_X_OH_NH_sub_2_sub_with_VO_OR_sub_3_sub_R_Et_nPr_structure_magnetic_susceptibility_and_ROP_capability/25359760 |
| DOI: | 10.17028/rd.lboro.25359760.v1 |
| الاتاحة: | https://doi.org/10.17028/rd.lboro.25359760.v1 https://figshare.com/articles/dataset/Supplementary_information_files_for_Reaction_of_Ph_sub_2_sub_C_X_CO_sub_2_sub_H_X_OH_NH_sub_2_sub_with_VO_OR_sub_3_sub_R_Et_nPr_structure_magnetic_susceptibility_and_ROP_capability/25359760 |
| Rights: | CC BY-NC 3.0 |
| رقم الانضمام: | edsbas.BA948D17 |
| قاعدة البيانات: | BASE |
| DOI: | 10.17028/rd.lboro.25359760.v1 |
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