Academic Journal
Preparation of pyridine-3,4-diols, their crystal packing and their use as precursors for palladium-catalyzed cross-coupling reactions
| العنوان: | Preparation of pyridine-3,4-diols, their crystal packing and their use as precursors for palladium-catalyzed cross-coupling reactions |
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| المؤلفون: | Tilman Lechel, Irene Brüdgam, Hans-Ulrich Reissig |
| المصدر: | Beilstein Journal of Organic Chemistry, Vol 6, Iss 1, p 42 (2010) |
| بيانات النشر: | Beilstein-Institut |
| سنة النشر: | 2010 |
| المجموعة: | Directory of Open Access Journals: DOAJ Articles |
| مصطلحات موضوعية: | bisnonaflates, fluorescence, palladium catalysis, pyridine-3,4-diols, pyridines, Science, Organic chemistry, QD241-441 |
| الوصف: | A series of trifluoromethyl-substituted 3-alkoxypyridinol derivatives has been deprotected to furnish pyridine-3,4-diol derivatives in good yields. The X-ray crystal structure analysis proved that a 1:1 mixture of pyridine-3,4-diols and their pyridin-4-one tautomers exist in the solid state. Subsequent conversion into bis(perfluoroalkanesulfonate)s were smoothly achieved. The obtained compounds were used as substrates for palladium-catalyzed coupling reactions. Fluorescence measurements of the biscoupled products showed a maximum of emission in the violet region of the spectrum. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| تدمد: | 1860-5397 |
| Relation: | https://doi.org/10.3762/bjoc.6.42; https://doaj.org/toc/1860-5397; https://doaj.org/article/fd8c80c049044df59c5957a00690db65 |
| DOI: | 10.3762/bjoc.6.42 |
| الاتاحة: | https://doi.org/10.3762/bjoc.6.42 https://doaj.org/article/fd8c80c049044df59c5957a00690db65 |
| رقم الانضمام: | edsbas.B995D9B5 |
| قاعدة البيانات: | BASE |
Full Text Finder | تدمد: | 18605397 |
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| DOI: | 10.3762/bjoc.6.42 |