Academic Journal
A Series of Low‐Coordinate Iron Selenido Complexes: Reactivity of a Linear Iron(I) Silylamide towards Selenium
| العنوان: | A Series of Low‐Coordinate Iron Selenido Complexes: Reactivity of a Linear Iron(I) Silylamide towards Selenium |
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| المؤلفون: | Schneider, Christian, Ivlev, Sergei, Werncke, C. Gunnar |
| المساهمون: | Deutsche Forschungsgemeinschaft |
| المصدر: | European Journal of Inorganic Chemistry ; volume 26, issue 8 ; ISSN 1434-1948 1099-0682 |
| بيانات النشر: | Wiley |
| سنة النشر: | 2023 |
| المجموعة: | Wiley Online Library (Open Access Articles via Crossref) |
| الوصف: | A variety of different low‐coordinate iron selenide complexes is reported. These are obtained by reaction of the linear iron(I) silylamide K{18c6}[Fe(N(Dipp)SiMe 3 ) 2 ] (Dipp=2,6‐diisopropylphenyl) with red selenium. Careful adjustment of the reaction conditions results in the formation of unique low‐coordinate selenido iron complexes, namely a monoselenide bridged [2Fe−1Se] 2+ complex, as well as mononuclear iron per‐ and triselenides. Further, C−H bond activation of one of the silylamide ligands by a putative terminal iron monoselenide is observed. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| DOI: | 10.1002/ejic.202200706 |
| الاتاحة: | http://dx.doi.org/10.1002/ejic.202200706 https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.202200706 https://onlinelibrary.wiley.com/doi/full-xml/10.1002/ejic.202200706 |
| Rights: | http://creativecommons.org/licenses/by-nc-nd/4.0/ |
| رقم الانضمام: | edsbas.B93DDB55 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1002/ejic.202200706 |
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