Academic Journal
Release of nanoparticles in the environment and catalytic converters ageing
| العنوان: | Release of nanoparticles in the environment and catalytic converters ageing |
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| المؤلفون: | Navarro-Espinoza, S., Meza-Figueroa, D., Guzmán, R., Duarte-Moller, A., Esparza-Ponce, H., Paz-Moreno, F., González-Grijalva, B., Álvarez-Bajo, O., Schiavo, B., Soto-Puebla, D., Pedroza-Montero, M. |
| المساهمون: | Department of Chemical and Environmental Engineering, University of Arizona |
| المصدر: | Nanomaterials |
| بيانات النشر: | MDPI |
| سنة النشر: | 2021 |
| المجموعة: | The University of Arizona: UA Campus Repository |
| مصطلحات موضوعية: | Non-exhaust emissions, Refractory nanoparticles, Sintering nanoparticles, Vehicle catalyst, Washcoat loss |
| الوصف: | A Three-Way Catalyst (TWC) contains a cordierite ceramic monolith coated with a layer of Al2 O3, Cex Zr1−x O2 and platinoids mixture. Under standard operation, the platinoid concentration decreases, exposing the remaining washcoat structure. After that particle release stage, the sintering process follows where the crystalline Cex Zr1−x O2 solution is broken and begins to separate into ZrO2 and CeO2 phases. ZrO2 is released to the environment as micro and nanoparticles, while a small amount of CeO2 generates a new Alx Ce1−x O2 composite. The main effect of Ce capture is the growth in the size of the polycrystal structure from 86.13 ± 16.58 nm to 225.35 ± 69.51 nm. Moreover, a transformation of cordierite to mullite was identified by XRD analysis. Raman spectra showed that the oxygen vacancies (Vö) concentration decreased as Cex Zr1−x O2 phases separation occurred. The SEM-EDS revealed the incorporation of new spurious elements and microfractures favouring the detachment of the TWC support structure. The release of ultrafine particles is a consequence of catalytic devices overusing. The emission of refractory micro to nanocrystals to the atmosphere may represent an emerging public health issue underlining the importance of implementing strict worldwide regulations on regular TWCs replacement. © 2021 by the authors. Licensee MDPI, Basel, Switzerland. ; Open access journal ; This item from the UA Faculty Publications collection is made available by the University of Arizona with support from the University of Arizona Libraries. If you have questions, please contact us at repository@u.library.arizona.edu. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| تدمد: | 2079-4991 |
| Relation: | Navarro-Espinoza, S., Meza-Figueroa, D., Guzmán, R., Duarte-Moller, A., Esparza-Ponce, H., Paz-Moreno, F., González-Grijalva, B., Álvarez-Bajo, O., Schiavo, B., Soto-Puebla, D., & Pedroza-Montero, M. (2021). Release of nanoparticles in the environment and catalytic converters ageing. Nanomaterials.; http://hdl.handle.net/10150/663010; Nanomaterials |
| DOI: | 10.3390/nano11123406 |
| الاتاحة: | http://hdl.handle.net/10150/663010 https://doi.org/10.3390/nano11123406 |
| Rights: | Copyright © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). ; https://creativecommons.org/licenses/by/4.0/ |
| رقم الانضمام: | edsbas.B7F46A11 |
| قاعدة البيانات: | BASE |
Full Text Finder | تدمد: | 20794991 |
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| DOI: | 10.3390/nano11123406 |