التفاصيل البيبلوغرافية
| العنوان: |
K 5 Mg 2 La 3 (BO 3 ) 6 : An Efficient, Deep-Ultraviolet Nonlinear Optical Material |
| المؤلفون: |
Runqing Liu (10838180), Hongping Wu (1568653), Hongwei Yu (3139), Zhanggui Hu (1974286), Jiyang Wang (1670281), Yicheng Wu (453327) |
| سنة النشر: |
2021 |
| المجموعة: |
Smithsonian Institution: Digital Repository |
| مصطلحات موضوعية: |
Microbiology, Astronomical and Space Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, Physical Sciences not elsewhere classified, KH, BO 3, KBBF, deep-UV NLO crystal, k 5 Mg 2 La 3, crystal layer habit, noncentrosymmetric space group P 31 m, KMLBO, PO, SHG, Deep-Ultraviolet Nonlinear Optical ., crystal layer habit limit |
| الوصف: |
KBe 2 BO 3 F 2 (KBBF) is the sole nonlinear optical (NLO) crystal that can practically generate deep-ultraviolet (UV) coherent light by a direct second-harmonic generation (SHG) process. However, the toxic BeO and crystal layer habit limit its application. With this background, a new beryllium-free borate, K 5 Mg 2 La 3 (BO 3 ) 6 (KMLBO), has been designed and synthesized through a high-temperature solution method. KMLBO crystallizes into the noncentrosymmetric space group P 31 m (No. 157) and features a three-dimensional framework structure consisting of alveolate [LaBO 3 ] ∞ layers further tightly bound via interlayer [BO 3 ] 3– groups. KMLBO not only exhibits desirable performances including deep-UV transparency, large SHG (∼3.1 × KH 2 PO 4 ), and phase-matchability but also overcomes the crystal layer habit of KBBF, demonstrating that it is a potential deep-UV NLO crystal. |
| نوع الوثيقة: |
dataset |
| اللغة: |
unknown |
| Relation: |
https://figshare.com/articles/dataset/K_sub_5_sub_Mg_sub_2_sub_La_sub_3_sub_BO_sub_3_sub_sub_6_sub_An_Efficient_Deep-Ultraviolet_Nonlinear_Optical_Material/14635397 |
| DOI: |
10.1021/acs.chemmater.1c01274.s002 |
| الاتاحة: |
https://doi.org/10.1021/acs.chemmater.1c01274.s002 |
| Rights: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.B3985F19 |
| قاعدة البيانات: |
BASE |