Academic Journal
Enantiospecific Synthesis of 1,3-Disubstituted Allenes from Propargylic Carbonates through a Borylation-1,2-Elimination Process
| العنوان: | Enantiospecific Synthesis of 1,3-Disubstituted Allenes from Propargylic Carbonates through a Borylation-1,2-Elimination Process |
|---|---|
| المؤلفون: | Jarava Barrera, Carlos, Parra Sánchez, Alejandro, Quesada, Sergio, Orgaz Gordillo, Sergio, Fernández de la Pradilla, Roberto, Viso, Alma, Teresa Ojeda, Javier, Alonso Montero, María Inés, Tortosa Manzanares, Mariola |
| المساهمون: | UAM. Departamento de Química Orgánica |
| بيانات النشر: | Wiley |
| سنة النشر: | 2024 |
| المجموعة: | Universidad Autónoma de Madrid (UAM): Biblos-e Archivo |
| مصطلحات موضوعية: | 1,2-anti-elimination, Allenes, Boronates, Propargylic carbonates, TBAF, Química |
| الوصف: | An array of enantioenriched vinyl boronates bearing an allylic carbonate moiety have been prepared through selective hydroboration of propargyl carbonates. Treatment of these vinyl boronates with TBAF in THF affords enantioenriched 1,3- disubstituted allenes through a novel 1,2-anti elimination in good yields and high enantiospecificities ; We thank MINECO (CTQ2016-78779-R) and MICINN (PID2019-107380GB I00) for financial support |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | application/pdf |
| اللغة: | English |
| Relation: | Advanced Synthesis and Catalysis; https://doi.org/10.1002/adsc.202300813; Gobierno de España. CTQ2016-78779; Gobierno de España. PID2019-107380GB-I; Advanced Synthesis and Catalysis (2023): 1-7; 1615-4150 (print); 1615-4169 (online); http://hdl.handle.net/10486/709922 |
| DOI: | 10.1002/adsc.202300813 |
| الاتاحة: | http://hdl.handle.net/10486/709922 https://doi.org/10.1002/adsc.202300813 |
| Rights: | © 2023 The Authors ; Reconocimiento – NoComercial ; openAccess |
| رقم الانضمام: | edsbas.B29D98E2 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1002/adsc.202300813 |
|---|