التفاصيل البيبلوغرافية
العنوان: |
High-resolution analysis of the v6, v17, and v21 bands of dimethyl ether |
المؤلفون: |
Coudert, Laurent C L, Çarçabal, Pierre, Chevalier, Michèle, Broquier, Michel, Hepp, Martin, Herman, Michel |
المصدر: |
Journal of Molecular Spectroscopy, 212 (2 |
سنة النشر: |
2002 |
المجموعة: |
DI-fusion : dépôt institutionnel de l'Université libre de Bruxelles (ULB) |
مصطلحات موضوعية: |
Optique, Physique atomique et moléculaire, Spectroscopie [état condense], Spectroscopie [électromagnétisme, acoustique], Chimie théorique, Physico-chimie générale, Dimethyl ether, Infrared, Jet-cooled FT spectroscopy, Large amplitude motion, Rotational analysis, Spectrum, Tunneling splitting |
الوصف: |
The v6, v17, and v21 fundamental bands of dimethyl ether have been assigned and rotationally analyzed. The spectra used were recorded at 0.005 cm−1 spectral resolution with a Fourier-transform spectrometer coupled to a supersonic molecular beam leading to a rotational temperature of about 70 K. The v6 and v21 bands do not seem to be perturbed and the analysis of the rotational structure leads to band centers located at 933.906 6(9) and 1 103.951(1) cm−1, respectively, and to accurate rotational and centrifugal distortion constants. For the v17 band at 2817.385(2) cm−1, only the P and R branches could be assigned. © 2002 Elsevier Science (USA). ; SCOPUS: ar.j ; info:eu-repo/semantics/published |
نوع الوثيقة: |
article in journal/newspaper |
وصف الملف: |
No full-text files |
اللغة: |
English |
Relation: |
uri/info:doi/10.1006/jmsp.2002.8541; uri/info:scp/0036290385; http://hdl.handle.net/2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/247255 |
الاتاحة: |
http://hdl.handle.net/2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/247255 |
رقم الانضمام: |
edsbas.B0AFE1EC |
قاعدة البيانات: |
BASE |