Academic Journal
Tetrahydroxydiboron (Bis‐boric Acid): a Versatile Reagent for Borylation, Hydrogenation, Catalysis, Radical Reactions and H 2 Generation
| العنوان: | Tetrahydroxydiboron (Bis‐boric Acid): a Versatile Reagent for Borylation, Hydrogenation, Catalysis, Radical Reactions and H 2 Generation |
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| المؤلفون: | Zhao, Qiuxia, Liu, Xiang, Astruc, Didier |
| المساهمون: | Université de Bordeaux, National Natural Science Foundation of China |
| المصدر: | European Journal of Inorganic Chemistry ; volume 26, issue 11 ; ISSN 1434-1948 1099-0682 |
| بيانات النشر: | Wiley |
| سنة النشر: | 2023 |
| المجموعة: | Wiley Online Library (Open Access Articles via Crossref) |
| الوصف: | Diboron compounds with a B−B bond, discovered with B 2 Cl 4 a century ago, have been developed only since the turn of this century for catalyzed borylation reactions, mostly with the well‐know reagent bis(binacolato)diboron, (B 2 pin 2 ). On the other hand, chemistry of tetrahydroxydiboron (THDB), also named bis‐boric acid, is relatively underdeveloped. In this review, the properties of THDB as a borylation, reductant (including transfer hydrogenation), catalyst, source of radicals and generator of H 2 from water upon hydrolysis are summarized. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| DOI: | 10.1002/ejic.202300024 |
| الاتاحة: | http://dx.doi.org/10.1002/ejic.202300024 https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.202300024 https://onlinelibrary.wiley.com/doi/full-xml/10.1002/ejic.202300024 |
| Rights: | http://creativecommons.org/licenses/by/4.0/ |
| رقم الانضمام: | edsbas.AB161DDB |
| قاعدة البيانات: | BASE |
| DOI: | 10.1002/ejic.202300024 |
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