Academic Journal
Successful amino-grafting functionalization of MIL-53(Al) through impulse dielectric barrier discharge plasma for hydrogen storage
| العنوان: | Successful amino-grafting functionalization of MIL-53(Al) through impulse dielectric barrier discharge plasma for hydrogen storage |
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| المؤلفون: | Najah, A., Jean-Marie-Desiree, R., Boivin, D., Canevesi, R. Luan Sehn, Noël, C., Izquierdo, M.T., Celzard, A., Fierro, Vanessa, de Poucques, Ludovic, Henrion, G., Cuynet, Stéphane |
| المساهمون: | Institut Jean Lamour (IJL), Institut de Chimie - CNRS Chimie (INC-CNRS)-Université de Lorraine (UL)-Centre National de la Recherche Scientifique (CNRS), Instituto de Carboquimica (ICB), Consejo Superior de Investigaciones Cientificas España = Spanish National Research Council Spain (CSIC), Institut universitaire de France (IUF), Ministère de l'Education nationale, de l’Enseignement supérieur et de la Recherche (M.E.N.E.S.R.), HyPE project (FRCR program funded by Région Grand-Est ), ANR-20-CE05-0013,SYNYERGY,Synthèse de MOFs hYbrides foNctionnalisés Et catalysés pouR le stockaGe de l'hYdrogène(2020), ANR-22-PEHY-0007,SOLHYD,SOLid storage of HYDdrogen: new strategies, new materials(2022), European Project |
| المصدر: | ISSN: 0360-3199. |
| بيانات النشر: | HAL CCSD Elsevier |
| سنة النشر: | 2024 |
| المجموعة: | Université de Lorraine: HAL |
| مصطلحات موضوعية: | Plasma functionalization IDBD MIL-53(Al) NH 3 hydrogen storage, Plasma functionalization, IDBD, MIL-53(Al), NH 3, hydrogen storage, [PHYS]Physics [physics] |
| الوصف: | International audience ; The present study investigates the functionalization of a commercial Metal-Organic Framework (MOF) named “MIL-53(Al)” using an NH3 impulse dielectric barrier discharge (IDBD) plasma treatment. The main objective of this research is to assess the efficacy of the IDBD treatment in grafting nitrogenous groups onto the MOF's organic ligand. Additionally, the impact of the plasma functionalization on the hydrogen adsorption capacities of the “MIL-53(Al)” after IDBD treatment is also studied. In order to accomplish these objectives, plasma diagnostics and comprehensive material characterization techniques are utilized. Structural and thermal analysis by HT-XRD and TGA-MS respectively, indicate the excellent thermal and chemical stability of the material against high temperatures and ammonia. Chemical analysis of the materials by XPS shows that the IDBD treatment effectively functionalizes the MIL-53(Al) by substituting a carbon with a nitrogen within the organic ligand. Finally, the analysis of the hydrogen adsorption capacities at 1 bar and 25 °C reveals that the amount of hydrogen stored in the MIL-53(Al) treated by IDBD is significantly higher. Specifically, the amount of hydrogen stored surpassed the untreated MIL-53(Al) by approximately 50%. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| Relation: | hal-04489035; https://hal.univ-lorraine.fr/hal-04489035; https://hal.univ-lorraine.fr/hal-04489035/document; https://hal.univ-lorraine.fr/hal-04489035/file/MIL-53%20Al%20H2.pdf |
| DOI: | 10.1016/j.ijhydene.2024.02.157 |
| الاتاحة: | https://hal.univ-lorraine.fr/hal-04489035 https://hal.univ-lorraine.fr/hal-04489035/document https://hal.univ-lorraine.fr/hal-04489035/file/MIL-53%20Al%20H2.pdf https://doi.org/10.1016/j.ijhydene.2024.02.157 |
| Rights: | http://creativecommons.org/licenses/by-nc-nd/ |
| رقم الانضمام: | edsbas.AAA7A09B |
| قاعدة البيانات: | BASE |
| DOI: | 10.1016/j.ijhydene.2024.02.157 |
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