التفاصيل البيبلوغرافية
| العنوان: |
Construction of Axially Chiral Arylborons via Atroposelective Miyaura Borylation |
| المؤلفون: |
Kai Yang (73590), Yanfei Mao (5802728), Jie Xu (34477), Hao Wang (39217), Yong He (115255), Wangyang Li (1471888), Qiuling Song (1393048) |
| سنة النشر: |
2021 |
| المجموعة: |
Smithsonian Institution: Digital Repository |
| مصطلحات موضوعية: |
Biochemistry, Genetics, Molecular Biology, Pharmacology, Biotechnology, Immunology, Developmental Biology, Chemical Sciences not elsewhere classified, chiral arylborons, Axially Chiral Arylborons, unsymmetrical diboron reagents, chiral boron chemistry, substrate scope, reaction features, atropisomeric arylborons, Atroposelective Miyaura Borylation, chiral chemistry |
| الوصف: |
Compared with the well-developed centrally chiral boron chemistry, C–B axially chiral chemistry remains elusive and challenging. Herein we report the first atroposelective Miyaura borylation of bromoarenes with unsymmetrical diboron reagents for the direct catalytic synthesis of optically active atropisomeric arylborons. This reaction features broad substrate scope and produces axially chiral arylborons with high yields and good enantioselectivities. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| Relation: |
https://figshare.com/articles/journal_contribution/Construction_of_Axially_Chiral_Arylborons_via_Atroposelective_Miyaura_Borylation/14866885 |
| DOI: |
10.1021/jacs.1c04345.s001 |
| الاتاحة: |
https://doi.org/10.1021/jacs.1c04345.s001 |
| Rights: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.A887A17B |
| قاعدة البيانات: |
BASE |