Academic Journal
Role and importance of solvents for the fractionation of lignocellulosic biomass
| العنوان: | Role and importance of solvents for the fractionation of lignocellulosic biomass |
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| المؤلفون: | Paulsen Thoresen P., Lange H., Rova U., Christakopoulos P., Matsakas L. |
| المساهمون: | Paulsen Thoresen, P, Lange, H, Rova, U, Christakopoulos, P, Matsakas, L |
| بيانات النشر: | Elsevier BV NL |
| سنة النشر: | 2023 |
| المجموعة: | Università degli Studi di Milano-Bicocca: BOA (Bicocca Open Archive) |
| مصطلحات موضوعية: | Dissolution, Fractionation, Lignocellulose, Solvation, Solvent |
| الوصف: | Lignocellulosic biomass is one of the most important renewable materials to replace carbon-based fossil resources. Solvent-based fractionation is a promising route for fractionation of biomass into its major components. Processing is governed by the employed solvent-systems properties. This review sheds light on the factors governing both dissolution and potential reactivities of the chemical structures present in lignocellulose, highlighting how proper understanding of the underlying mechanisms and interactions between solute and solvent help to choose proper systems for specific fractionation needs. Structural and chemical differences between the carbohydrate-based structural polymers and lignin require very different solvents capabilities in terms of causing and eventually stabilizing conformational changes and consequent activation of bonds to be cleaved by other active components in the. A consideration of potential depolymerization events during dissolution and energetic aspects of the dissolution process considering the contribution of polymer functionalities allow for a mapping of solvent suitability for biomass fractionation. |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | STAMPA |
| اللغة: | English |
| Relation: | info:eu-repo/semantics/altIdentifier/pmid/36496118; info:eu-repo/semantics/altIdentifier/wos/WOS:000912289400001; volume:369; issue:February 2023; journal:BIORESOURCE TECHNOLOGY; https://hdl.handle.net/10281/402898; info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-85144866454 |
| DOI: | 10.1016/j.biortech.2022.128447 |
| الاتاحة: | https://hdl.handle.net/10281/402898 https://doi.org/10.1016/j.biortech.2022.128447 |
| Rights: | info:eu-repo/semantics/openAccess |
| رقم الانضمام: | edsbas.A8487AA1 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1016/j.biortech.2022.128447 |
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