Conference
A two-dimensional magnetic architecture with bridging polynitrile and 2,2′-bipyrimidine ligands
| العنوان: | A two-dimensional magnetic architecture with bridging polynitrile and 2,2′-bipyrimidine ligands |
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| المؤلفون: | Galán-Mascarós, J.-R., Thetiot, Franck, Triki, Smail, Sala Pala, J., Dunbar, K.R. |
| المساهمون: | Chimie, Electrochimie Moléculaires et Chimie Analytique (CEMCA), Université de Brest (UBO)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS)-Institut Brestois Santé Agro Matière (IBSAM), Université de Brest (UBO), Batail P., Canadell E., Dupuis N., Fourmigue M., Jerome D., Pouget J.-P. |
| المصدر: | ISCOM 2003: 5th International Symposium on Crystalline Organic Metals, Superconductors and Ferromagnets ; https://hal.univ-brest.fr/hal-01763884 ; ISCOM 2003: 5th International Symposium on Crystalline Organic Metals, Superconductors and Ferromagnets, 2004, Unknown, Unknown Region. pp.625-626, ⟨10.1051/jp4:2004114148⟩ |
| بيانات النشر: | CCSD |
| سنة النشر: | 2004 |
| المجموعة: | Université de Bretagne Occidentale: HAL |
| مصطلحات موضوعية: | Antiferromagnetism, Negative ions, Synthesis (chemical), X ray crystallography, 2.2'-bipyrimidine, Cobalt complexes, Magnetic measurements, Organic polymers, [CHIM]Chemical Sciences |
| جغرافية الموضوع: | Unknown, Unknown Region |
| الوصف: | cited By 7 ; International audience ; A new polymeric, two-dimensional compound [Co2(bpym)(dcne) 4 (H2O)2] (1) (dcne = [(CN)2CC(O) OEt)]- = 2,2-dicyano-1-ethoxyethenolate anion and bpym = 2,2'-bipyrimidine) has been synthesized and characterized by X-ray crystallography. The structure is monoclinic space group P21/a and consists of two-dimensional networks of octahedrally coordinated Co(II) ions, bridged by bis-bidentate 2,2'-bipyrimidine and μ2-dcne anions. Magnetic measurements revealed a broad maximum in the xm vs T plot at 20 K which is characteristic of antiferromagnetic exchange between the high spin cobalt(II) centres. © EDP Sciences. |
| نوع الوثيقة: | conference object |
| اللغة: | English |
| DOI: | 10.1051/jp4:2004114148 |
| الاتاحة: | https://hal.univ-brest.fr/hal-01763884 https://doi.org/10.1051/jp4:2004114148 |
| رقم الانضمام: | edsbas.A44E1D7E |
| قاعدة البيانات: | BASE |
| DOI: | 10.1051/jp4:2004114148 |
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