Academic Journal

Investigating the Metallic Nanoparticles Decoration on Reduced Graphene Oxide-Based Sensors Used to Detect Sulfur Dioxide

التفاصيل البيبلوغرافية
العنوان: Investigating the Metallic Nanoparticles Decoration on Reduced Graphene Oxide-Based Sensors Used to Detect Sulfur Dioxide
المؤلفون: Ruiz, Elisa, Varenne, Christelle, de Lima, Bruno, Gueye, Thiaka, Pauly, Alain, Brunet, Jérôme, Mastelaro, Valmor, Ndiaye, Amadou
المساهمون: Institut Pascal (IP), Centre National de la Recherche Scientifique (CNRS)-Université Clermont Auvergne (UCA)-Institut national polytechnique Clermont Auvergne (INP Clermont Auvergne), Université Clermont Auvergne (UCA)-Université Clermont Auvergne (UCA), Universidade de São Paulo = University of São Paulo (USP), Ministère de L’enseignement supérieur et de la recherche (MESR)- Research Center “Innovation Transportation and Production Systems” of the I-SITE CAP 20-25- Fundação de Amparo à Pesquisa do Estado de São Paulo—FAPESP (Grant no 2018/07517-2 and 2013/07296-2).
المصدر: ISSN: 2227-9040 ; Chemosensors ; https://hal.science/hal-04567602 ; Chemosensors, 2024, 12 (2), pp.24. ⟨10.3390/chemosensors12020024⟩.
بيانات النشر: HAL CCSD
MDPI
سنة النشر: 2024
المجموعة: HAL Clermont Auvergne (Université Blaise Pascal Clermont-Ferrand / Université d'Auvergne)
مصطلحات موضوعية: rGO, nanoparticles, nanocomposites, functionalization, gas sensors, SO2, NPs loading, physical decoration, chemical decoration, [CHIM.MATE]Chemical Sciences/Material chemistry, [CHIM.ANAL]Chemical Sciences/Analytical chemistry, [SDE.IE]Environmental Sciences/Environmental Engineering
الوصف: International audience ; This paper presents the impact of the decoration of reduced graphene oxide (rGO) with metallic nanoparticles to detect sulfur dioxide (SO2). Copper and platinum were employed to produce metal nanoparticles (NPs) for the chemical and physical decoration of rGO to form the nanocomposites (rGO/NPs). We optimized NP loading by varying the concentrations of metal ions and deposition times for chemical and physical decoration, respectively. The chemical decoration presents a random nanoparticle distribution on the rGO surface with a broad particle size distribution (1 to 100 nm with a majority less than 40 nm). In comparison, the physical decoration presents uniformly distributed nanoparticles with particles of a size between 1 and 20 nm, with a majority less than 10 nm. The chemically decorated structures present the best gas responses and show that lower NP loading provides better responses. The nanocomposites present responses owing to a better synergy between NPs and the rGO surface, combined with the catalytic action of the NPs on the rGO. The physical decoration allows higher NP surface coverage than the chemical one but implies a lower remaining rGO naked surface for gaseous molecule interaction. These results illustrate that the NPs’ surface and the uncovered rGO contribute to the gas response.
نوع الوثيقة: article in journal/newspaper
اللغة: English
Relation: hal-04567602; https://hal.science/hal-04567602; https://hal.science/hal-04567602/document; https://hal.science/hal-04567602/file/NPs%20Decor236.pdf
DOI: 10.3390/chemosensors12020024
الاتاحة: https://hal.science/hal-04567602
https://hal.science/hal-04567602/document
https://hal.science/hal-04567602/file/NPs%20Decor236.pdf
https://doi.org/10.3390/chemosensors12020024
Rights: http://creativecommons.org/licenses/by/ ; info:eu-repo/semantics/OpenAccess
رقم الانضمام: edsbas.9F81B7F
قاعدة البيانات: BASE
الوصف
DOI:10.3390/chemosensors12020024