Academic Journal
Synthesis and structural consideration of 1‐chloro‐ N, N′, N″‐tris(pentafluorophenyl)azagermatrane: Azagermatrane with the shortest intramolecular N → Ge bond
| العنوان: | Synthesis and structural consideration of 1‐chloro‐ N, N′, N″‐tris(pentafluorophenyl)azagermatrane: Azagermatrane with the shortest intramolecular N → Ge bond |
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| المؤلفون: | Lermontova, El'mira Kh., Churakov, Andrei V., Howard, Judith A. K., Oprunenko, Yuri F., Karlov, Sergey S., Zaitseva, Galina S. |
| المصدر: | Heteroatom Chemistry ; volume 19, issue 7, page 738-741 ; ISSN 1042-7163 1098-1071 |
| بيانات النشر: | Wiley |
| سنة النشر: | 2008 |
| المجموعة: | Wiley Online Library (Open Access Articles via Crossref) |
| الوصف: | Two compounds of a novel‐type azagermatrane, N(CH 2 CH 2 NC 6 F 5 ) 3 Ge‐Hal: HalCl ( 1 ), Br ( 2 ), were prepared via a metathetical reaction of trilithium salt of tetramine, N[CH 2 CH 2 N(Li)C 6 F 5 ] 3 , with corresponding GeHal 4 . A single crystal structure of 1 was determined by the X‐ray diffraction study: The compound shows the strongest transannular N ax → Ge interaction (2.148(7) Å) among other studied azagermatranes. © 2008 Wiley Periodicals, Inc. Heteroatom Chem 19:738–741, 2008; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20476 |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| DOI: | 10.1002/hc.20476 |
| الاتاحة: | http://dx.doi.org/10.1002/hc.20476 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fhc.20476 https://onlinelibrary.wiley.com/doi/pdf/10.1002/hc.20476 |
| Rights: | http://onlinelibrary.wiley.com/termsAndConditions#vor |
| رقم الانضمام: | edsbas.9D48CEAD |
| قاعدة البيانات: | BASE |
| DOI: | 10.1002/hc.20476 |
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