Academic Journal
A new 3D supramolecular Cu(ii) framework: Crystal structure and photocatalytic characteristics
| العنوان: | A new 3D supramolecular Cu(ii) framework: Crystal structure and photocatalytic characteristics |
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| المؤلفون: | Li Jing, Ren Hongjiang, Li Jiangtao, Wang Liuchang |
| المصدر: | Open Chemistry, Vol 21, Iss 1, Pp 121860-16 (2023) |
| بيانات النشر: | De Gruyter |
| سنة النشر: | 2023 |
| المجموعة: | Directory of Open Access Journals: DOAJ Articles |
| مصطلحات موضوعية: | cu(ii) compound, tetranuclear cluster, supramolecular framework, photocatalysis, Chemistry, QD1-999 |
| الوصف: | Reported here is a new Cu(ii) compound with the formula of {Cu4(μ 2-Cl)6(μ 4-O)(4-NH2-py)4}n (1, 4-NH2-py = 4-amino-pyridine). The analysis of X-ray diffraction shows that the complex 1 indicates a 0D separated skeleton with {Cu4(μ 2-Cl)6(μ 4-O)} tetranuclear cluster. The interactions of H-bond between the amino groups and μ 2-Cl anions from adjacent 0D cluster further extended this 0D cluster into a 3D supramolecular framework. In addition, this compound has excellent photocatalytic activities for the degradation of methyl blue under UV radiation. The cyclic testing results indicate that complex 1 exhibits good recyclability, as it can be repeated for as many as five cycles with no noticeable loss of performance, revealing its potential application in pollutant degradation within the environmental field. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| تدمد: | 2391-5420 |
| Relation: | https://doi.org/10.1515/chem-2023-0151; https://doaj.org/toc/2391-5420; https://doaj.org/article/a63c79120f0c473990dc6f5541455023 |
| DOI: | 10.1515/chem-2023-0151 |
| الاتاحة: | https://doi.org/10.1515/chem-2023-0151 https://doaj.org/article/a63c79120f0c473990dc6f5541455023 |
| رقم الانضمام: | edsbas.9C187C97 |
| قاعدة البيانات: | BASE |
Full Text Finder | تدمد: | 23915420 |
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| DOI: | 10.1515/chem-2023-0151 |