Academic Journal
Fast and Slow Laser-Stimulated Degradation of Mn-Doped Li4Ti5O12
| العنوان: | Fast and Slow Laser-Stimulated Degradation of Mn-Doped Li4Ti5O12 |
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| المؤلفون: | Nikiforov, A. A., K. , Kuznetsov, D., Nasara, R. N., Govindarajan, K., Lin, S. -K., Pelegov, D. V. |
| المصدر: | Batteries |
| بيانات النشر: | MDPI |
| سنة النشر: | 2022 |
| المجموعة: | Ural Federal University (URFU): ELAR / Уральский федеральный университет: электронный архив УрФУ |
| مصطلحات موضوعية: | AMORPHIZATION, LASER ABLATION, LASER-MATTER INTERACTION, LITHIUM TITANATE, RAMAN SPECTROSCOPY, ANODES, DEGRADATION, LITHIUM COMPOUNDS, LITHIUM-ION BATTERIES, MANGANESE COMPOUNDS, NONDESTRUCTIVE EXAMINATION, TITANIUM COMPOUNDS, AMORPHIZATIONS, ANODE MATERIAL, DEGRADATION PROCESS, ELECTRONIC CONDUCTIVITY, HIGH POWER, LASER-MATTER INTERACTIONS, LASERS ABLATIONS, LIFESPANS, MN-DOPED |
| الوصف: | Lithium titanate (Li4Ti5O12) is a commercial anode material used for high-power and long-lifespan lithium batteries. The key drawback of this material is its low electronic conductivity. Although doping is commonly used to solve this problem, the introduction of dopants also diminished lattice stability. In this work, we studied fast and slow laser-induced degradation processes of single Mn-doped lithium titanate particles and proposed a physicochemical model of their degradation mechanism. We suppose that the preferable route of LTO alteration is the formation of amorphous phases rather than crystalline decomposition products. Our results may be useful for not only developing a nondestructive characterization tool utilizing Raman spectroscopy but also for understanding other degradation processes, including thermal alteration and structural changes caused by the intercalation/deintercalation cycles of lithium ions. © 2022 by the authors. ; Ministry of Science and Technology of the People's Republic of China, MOST, (110-2923-E-006-011, 111-2636-E-006-018) ; Ministry of Education and Science of the Russian Federation, Minobrnauka, (075-15-2021-677) ; Russian Science Foundation, RSF, (22-22-00350) ; Ural Federal University, UrFU, (2968) ; The research was funded by the Russian Science Foundation (project No 22-22-00350, https://rscf.ru/project/22-22-00350). The Raman spectra measurement and SEM imaging were made using equipment of the Ural Center for Shared Use “Modern nanotechnology” Ural Federal University (Reg. No 2968), supported by the Ministry of Science and Higher Education of the Russian Federation (Project No 075-15-2021-677). K.G. and S.k.-L. gratefully acknowledge the financial supports from the Ministry of Science and Technology (MOST) in Taiwan (111-2636-E-006-018 and 110-2923-E-006-011). |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | application/pdf |
| اللغة: | English |
| تدمد: | 2313-0105 |
| Relation: | info:eu-repo/grantAgreement/RSF//22-22-00350; Nikiforov, AA, Kuznetsov, DK, Nasara, RN, Govindarajan, K, Lin, S & Pelegov, DV 2022, 'Fast and Slow Laser-Stimulated Degradation of Mn-Doped Li4Ti5O12', Batteries, Том. 8, № 12, 251. https://doi.org/10.3390/batteries8120251; Nikiforov, A. A., Kuznetsov, D. K., Nasara, R. N., Govindarajan, K., Lin, S., & Pelegov, D. V. (2022). Fast and Slow Laser-Stimulated Degradation of Mn-Doped Li4Ti5O12. Batteries, 8(12), [251]. https://doi.org/10.3390/batteries8120251; Final; All Open Access; Gold Open Access; https://www.mdpi.com/2313-0105/8/12/251/pdf?version=1669251479; http://elar.urfu.ru/handle/10995/131346; 85144655575; 000900421900001 |
| DOI: | 10.3390/batteries8120251 |
| الاتاحة: | http://elar.urfu.ru/handle/10995/131346 https://www.mdpi.com/2313-0105/8/12/251/pdf?version=1669251479 https://doi.org/10.3390/batteries8120251 |
| Rights: | info:eu-repo/semantics/openAccess ; cc-by ; https://creativecommons.org/licenses/by/4.0/ |
| رقم الانضمام: | edsbas.9A33C12B |
| قاعدة البيانات: | BASE |
| تدمد: | 23130105 |
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| DOI: | 10.3390/batteries8120251 |