Academic Journal

Surface Plasmon Resonance-Induced Charge Transfer in Ag/Mercaptobenzoic Acid/Polyaniline Sandwich Structures

التفاصيل البيبلوغرافية
العنوان: Surface Plasmon Resonance-Induced Charge Transfer in Ag/Mercaptobenzoic Acid/Polyaniline Sandwich Structures
المؤلفون: Nannan Yang, Shuang Guo, Eungyeong Park, Yeonju Park, Jiku Wang, Lei Chen, Young Mee Jung
سنة النشر: 2024
المجموعة: Smithsonian Institution: Figshare
مصطلحات موضوعية: Medicine, Neuroscience, Biotechnology, Computational Biology, Space Science, Environmental Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, layered assembly method, increasing sputtering time, experimental findings demonstrated, enhanced raman scattering, 2d correlation spectroscopy, organic semiconductor system, composite system composed, surface plasmon resonance, excellent sers performance, induced charge transfer, charge transfer, pani system, red shift, probe molecule, novel possibilities, mercaptobenzoic acid, good stability, development opens, active substrates
الوصف: Tunable surface plasmon resonance (SPR) of silver (Ag) films fabricated via magnetron sputtering technology was achieved. The experimental findings demonstrated that the thickness of the Ag film gradually increased with increasing sputtering time, resulting in a red shift of the SPR peak. To investigate the charge transfer (CT) induced by SPR in a metal/probe molecule/organic semiconductor system, a composite system composed of Ag nanoparticles, mercaptobenzoic acid (MBA), and polyaniline (PANI) was prepared by a layered assembly method. Notably, the surface-enhanced Raman scattering (SERS) intensity of the Ag/MBA/PANI system increased significantly with the introduction of PANI. The contribution of CT was evaluated by using the CT degree of the Ag/MBA/PANI system. On the basis of these results, the CT direction was confirmed by 2D correlation spectroscopy, revealing that the Ag/MBA/PANI system had good stability and excellent SERS performance. This development opens up novel possibilities and perspectives for the fabrication of SERS-active substrates.
نوع الوثيقة: article in journal/newspaper
اللغة: unknown
Relation: https://figshare.com/articles/journal_contribution/Surface_Plasmon_Resonance-Induced_Charge_Transfer_in_Ag_Mercaptobenzoic_Acid_Polyaniline_Sandwich_Structures/25265896
DOI: 10.1021/acs.jpcc.4c00292.s001
الاتاحة: https://doi.org/10.1021/acs.jpcc.4c00292.s001
Rights: CC BY-NC 4.0
رقم الانضمام: edsbas.99A95522
قاعدة البيانات: BASE
الوصف
DOI:10.1021/acs.jpcc.4c00292.s001