Academic Journal
Catalytic Enantioselective Synthesis of Naturally Occurring Butenolides via Hetero-Allylic Alkylation and Ring Closing Metathesis
| العنوان: | Catalytic Enantioselective Synthesis of Naturally Occurring Butenolides via Hetero-Allylic Alkylation and Ring Closing Metathesis |
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| المؤلفون: | Mao, Bin, Geurts, Koen, Fañanás-Mastral, Martín, Zijl, Anthoni W. van, Fletcher, Stephen P., Minnaard, Adriaan J., Feringa, Bernard |
| المصدر: | Mao , B , Geurts , K , Fañanás-Mastral , M , Zijl , A W V , Fletcher , S P , Minnaard , A J & Feringa , B 2011 , ' Catalytic Enantioselective Synthesis of Naturally Occurring Butenolides via Hetero-Allylic Alkylation and Ring Closing Metathesis ' , Organic letters , vol. 13 , no. 5 , pp. 948-951 . https://doi.org/10.1021/ol102994q |
| سنة النشر: | 2011 |
| المجموعة: | University of Groningen research database |
| مصطلحات موضوعية: | TRANS-WHISKEY LACTONE, (+)-NEPHROSTERANIC ACID, (-)-ROCCELLARIC ACID, (+)-TRANS-WHISKEY LACTONE, (+)-TRANS-COGNAC LACTONE, PARACONIC ACIDS, GAMMA-LACTONES, ASYMMETRIC DIHYDROXYLATION, (-)-NEPHROSTERANIC ACID, (+)-ROCCELLARIC ACID |
| الوصف: | An efficient catalytic asymmetric synthesis of chiral γ-butenolides was developed based on the hetero-allylic asymmetric alkylation (h-AAA) in combination with ring closing metathesis (RCM). The synthetic potential of the h-AAA-RCM protocol was illustrated with the facile synthesis of (-)-whiskey lactone, (-)-cognac lactone, (-)-nephrosteranic acid, and (-)-roccellaric acid. |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | application/pdf |
| اللغة: | English |
| DOI: | 10.1021/ol102994q |
| الاتاحة: | https://hdl.handle.net/11370/6dc5ecc8-f9e5-4e0f-b8fd-63f1f797667c https://research.rug.nl/en/publications/6dc5ecc8-f9e5-4e0f-b8fd-63f1f797667c https://doi.org/10.1021/ol102994q https://pure.rug.nl/ws/files/2504531/2011OrgLettMaoSupp.pdf https://pure.rug.nl/ws/files/2504532/2011OrgLettMao.pdf |
| Rights: | info:eu-repo/semantics/openAccess |
| رقم الانضمام: | edsbas.98C08313 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1021/ol102994q |
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