Academic Journal

Carbon supported, Al doped-Li3V2(PO4)(3) as a high rate cathode material for lithium-ion batteries

التفاصيل البيبلوغرافية
العنوان: Carbon supported, Al doped-Li3V2(PO4)(3) as a high rate cathode material for lithium-ion batteries
المؤلفون: Cho, A. R., Son, J. N., Aravindan, V., Kim, H., Kang, K. S., Yoon, W. S., Kim, W. S., Lee, Y. S.
المساهمون: 강기석, Kang, K. S.
بيانات النشر: Royal Society of Chemistry
سنة النشر: 2020
المجموعة: Seoul National University: S-Space
مصطلحات موضوعية: DOPED LI3V2(PO4)(3), ELECTROCHEMICAL PERFORMANCE, PHOSPHATE, CAPACITY
الوصف: A high rate and high performance Li3V2(PO4)(3) cathode was prepared by applying a carbon coating and Al substitution using the conventional solid-state approach. X-Ray diffraction was used to observe the structural properties of the synthesized powders. The presence of the carbon coating was confirmed by HR-TEM and reflected well with the Raman analysis. The Li/C-Li3V1.98Al0.02(PO4)(3) cell displayed a discharge capacity of 182 mA h g(-1) between 3 and 4.8 V vs. Li at a current density of 0.1 mA cm(-1), which is similar to 20 mA h g(-1) higher than that of the native compound. The capacity retention was found to be 84 and 74% after 40 and 100 cycles, respectively. The C-Li3V1.98Al0.02(PO4)(3) powders demonstrated excellent rate performance at 20 C with a discharge capacity of similar to 120 mA h g(-1) over 100 cycles. The elevated temperature performance was also evaluated and found to be similar to that under room temperature conditions. ; Y ; 1
نوع الوثيقة: article in journal/newspaper
اللغة: unknown
تدمد: 0959-9428
Relation: Journal of Materials Chemistry, Vol.22 No.14, pp.6556-6560; 92864; https://hdl.handle.net/10371/165140; 000301459500009; 2-s2.0-84863337598
DOI: 10.1039/c2jm00022a
الاتاحة: https://hdl.handle.net/10371/165140
https://doi.org/10.1039/c2jm00022a
رقم الانضمام: edsbas.94B92254
قاعدة البيانات: BASE
الوصف
تدمد:09599428
DOI:10.1039/c2jm00022a