Academic Journal
Carbon supported, Al doped-Li3V2(PO4)(3) as a high rate cathode material for lithium-ion batteries
العنوان: | Carbon supported, Al doped-Li3V2(PO4)(3) as a high rate cathode material for lithium-ion batteries |
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المؤلفون: | Cho, A. R., Son, J. N., Aravindan, V., Kim, H., Kang, K. S., Yoon, W. S., Kim, W. S., Lee, Y. S. |
المساهمون: | 강기석, Kang, K. S. |
بيانات النشر: | Royal Society of Chemistry |
سنة النشر: | 2020 |
المجموعة: | Seoul National University: S-Space |
مصطلحات موضوعية: | DOPED LI3V2(PO4)(3), ELECTROCHEMICAL PERFORMANCE, PHOSPHATE, CAPACITY |
الوصف: | A high rate and high performance Li3V2(PO4)(3) cathode was prepared by applying a carbon coating and Al substitution using the conventional solid-state approach. X-Ray diffraction was used to observe the structural properties of the synthesized powders. The presence of the carbon coating was confirmed by HR-TEM and reflected well with the Raman analysis. The Li/C-Li3V1.98Al0.02(PO4)(3) cell displayed a discharge capacity of 182 mA h g(-1) between 3 and 4.8 V vs. Li at a current density of 0.1 mA cm(-1), which is similar to 20 mA h g(-1) higher than that of the native compound. The capacity retention was found to be 84 and 74% after 40 and 100 cycles, respectively. The C-Li3V1.98Al0.02(PO4)(3) powders demonstrated excellent rate performance at 20 C with a discharge capacity of similar to 120 mA h g(-1) over 100 cycles. The elevated temperature performance was also evaluated and found to be similar to that under room temperature conditions. ; Y ; 1 |
نوع الوثيقة: | article in journal/newspaper |
اللغة: | unknown |
تدمد: | 0959-9428 |
Relation: | Journal of Materials Chemistry, Vol.22 No.14, pp.6556-6560; 92864; https://hdl.handle.net/10371/165140; 000301459500009; 2-s2.0-84863337598 |
DOI: | 10.1039/c2jm00022a |
الاتاحة: | https://hdl.handle.net/10371/165140 https://doi.org/10.1039/c2jm00022a |
رقم الانضمام: | edsbas.94B92254 |
قاعدة البيانات: | BASE |
تدمد: | 09599428 |
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DOI: | 10.1039/c2jm00022a |