Academic Journal
Rhombohedral Iron Trifluoride with a Hierarchized Macroporous/Mesoporous Texture from Gaseous Fluorination of Iron Disilicide
| العنوان: | Rhombohedral Iron Trifluoride with a Hierarchized Macroporous/Mesoporous Texture from Gaseous Fluorination of Iron Disilicide |
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| المؤلفون: | Delbègue Diane, Guérin Katia, Laik Barbara, Pereira-Ramos Jean-Pierre, Sougrati Moulay-Tahar, Cénac-Morthe Céline |
| المصدر: | E3S Web of Conferences, Vol 16, p 08001 (2017) |
| بيانات النشر: | EDP Sciences |
| سنة النشر: | 2017 |
| المجموعة: | Directory of Open Access Journals: DOAJ Articles |
| مصطلحات موضوعية: | Environmental sciences, GE1-350 |
| الوصف: | Stable low temperature rhombohedral iron trifluoride has been obtained by the fluorination under the pure fluorine gas of iron disilicide. The combination of both unusual fluorination process and precursor avoids to get unhydrated crystalline FeF3 particles and allows the formation of hierarchized channels of mesoporous/macroporous texture favorable for lithium diffusion. The fluorination mechanism proceeds by temperature steps from the formation, for a fluorination temperature below 200 °C, of an amorphous phase and an intermediate iron difluoride identified mainly by 57Fe Mössbauer spectroscopy before getting, as soon as a fluorination temperature of 260 °C is reached, the rhombohedral FeF3. Both amorphous and crystallized samples display good ability for electrochemical process when used as cathode in lithium-ion battery. The low diameter of rhombohedral structure channels is balanced by an appropriate mesoporous texture and a capacity of 225 mAh.g−1 after 5 cycles for a discharge cut-off of 2.5 V vs. Li+/Li at a current density of C/20 has been obtained and stabilized at 95 mAh.g−1 after 116 cycles. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English French |
| تدمد: | 2267-1242 |
| Relation: | https://doi.org/10.1051/e3sconf/20171608001; https://doaj.org/toc/2267-1242; https://doaj.org/article/9797b84a50004cc984a683f8bae3354d |
| DOI: | 10.1051/e3sconf/20171608001 |
| الاتاحة: | https://doi.org/10.1051/e3sconf/20171608001 https://doaj.org/article/9797b84a50004cc984a683f8bae3354d |
| رقم الانضمام: | edsbas.93FC5A3B |
| قاعدة البيانات: | BASE |
Full Text Finder | تدمد: | 22671242 |
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| DOI: | 10.1051/e3sconf/20171608001 |