Academic Journal
Oxidation of alcohols and aldehydes with peracetic acid and a Mn(II)/Pyridin‐2‐carboxylato catalyst: substrate and continuous flow studies
| العنوان: | Oxidation of alcohols and aldehydes with peracetic acid and a Mn(II)/Pyridin‐2‐carboxylato catalyst: substrate and continuous flow studies |
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| المؤلفون: | Ryan, Ailbhe A., Dempsey, Seán D., Smyth, Megan, Fahey, Karen, Moody, Thomas S., Wharry, Scott, Dingwall, Paul, Rooney, David W., Thompson, Jillian M., Knipe, Peter C., Muldoon, Mark J. |
| المصدر: | Ryan , A A , Dempsey , S D , Smyth , M , Fahey , K , Moody , T S , Wharry , S , Dingwall , P , Rooney , D W , Thompson , J M , Knipe , P C & Muldoon , M J 2024 , ' Oxidation of alcohols and aldehydes with peracetic acid and a Mn(II)/Pyridin‐2‐carboxylato catalyst: substrate and continuous flow studies ' , ChemCatChem . https://doi.org/10.1002/cctc.202301709 |
| سنة النشر: | 2024 |
| المجموعة: | Queen's University Belfast: Research Portal |
| مصطلحات موضوعية: | Continuous flow, carbonyls, manganese, oxidation, peroxide |
| الوصف: | A homogeneous catalyst system consisting of Mn(OAc) 2 and 2-picolinic acid was studied for alcohol oxidation using peracetic acid as the oxidant. Catalyst loadings as low as 0.01 mol% could be utilized and the system compared well to other peroxide based methods. The utilization of continuous flow allowed the fast, exothermic reactions to be carried out in a safe and scalable manner. |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | application/pdf |
| اللغة: | English |
| DOI: | 10.1002/cctc.202301709 |
| الاتاحة: | https://pure.qub.ac.uk/en/publications/50dc497a-421c-4336-93a1-3a7f47c7f4f1 https://doi.org/10.1002/cctc.202301709 https://pureadmin.qub.ac.uk/ws/files/604955028/Oxidation_of_alcohols_and_aldehydes.pdf |
| Rights: | info:eu-repo/semantics/openAccess |
| رقم الانضمام: | edsbas.90D20A87 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1002/cctc.202301709 |
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