Academic Journal
Petroselinic acid purification and its use for the fermentation of new sophorolipids
| العنوان: | Petroselinic acid purification and its use for the fermentation of new sophorolipids |
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| المؤلفون: | Delbeke, Elisabeth, Everaert, Jonas, Uitterhaegen, Evelien, Verweire, Stijn, Verlee, Arno, Talou, Thierry, Soetaert, Wim, Van Bogaert, Inge, Stevens, Christian |
| المصدر: | AMB EXPRESS ; ISSN: 2191-0855 |
| سنة النشر: | 2016 |
| المجموعة: | Ghent University Academic Bibliography |
| مصطلحات موضوعية: | Chemistry, Sophorolipid, Fermentation, Starmerella bombicola, Petroselinic acid, Chemical derivatization, CANDIDA-BOMBICOLA, ARACHIDONIC-ACID, LIPIDS, BIOSURFACTANTS |
| الوصف: | Petroselinic acid, a positional isomer of oleic acid, was isolated from the vegetable oil of Coriandrum sativum fruits. This uncommon fatty acid was subsequently used as substrate for sophorolipid fermentation with a Starmerella bombicola lactone esterase overexpression (oe sble) strain. A petroselinic acid based diacetylated sophorolipid lactone was obtained in high purity without incorporation of de novo synthesized fatty acids such as oleic acid. A total production of 40 g/L was obtained. The petroselinic acid based sophorolipid lactone was subsequently hydrolyzed towards the petroselinic acid based sophorolipid acid. For both compounds, their critical micelle concentration (CMC) and corresponding surface tension were compared to their oleic acid based counterparts. Both petroselinic acid based sophorolipids displayed a much lower CMC value than their oleic acid based counterparts, although their minimal surface tension was the same. Besides, the sophorolipid fermentation product was chemically modified towards a novel C12 sophorolipid aldehyde. This derivative constitutes an interesting building block for further modification towards new-to-nature sophorolipids with high potential for self-assembly applications. |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | application/pdf |
| اللغة: | English |
| Relation: | https://biblio.ugent.be/publication/7177443; https://biblio.ugent.be/publication/7177443/file/7177471 |
| DOI: | 10.1186/s13568-016-0199-7 |
| الاتاحة: | https://biblio.ugent.be/publication/7177443 http://hdl.handle.net/1854/LU-7177443 https://doi.org/10.1186/s13568-016-0199-7 https://biblio.ugent.be/publication/7177443/file/7177471 |
| Rights: | Creative Commons Attribution 4.0 International Public License (CC-BY 4.0) ; info:eu-repo/semantics/openAccess |
| رقم الانضمام: | edsbas.8B0665C0 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1186/s13568-016-0199-7 |
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