التفاصيل البيبلوغرافية
| العنوان: |
Glass-transition-, melting-, and decomposition temperatures of tailored polyacrylates and polymethacrylates: General trends and structure-property relationships |
| المؤلفون: |
Fleischhaker, Friederike, Haehnel, Alexander, Misske, Andrea, Blanchot, Mathieu, Haremza, Sylke, Barner-Kowollik, Christopher |
| المصدر: |
Macromolecular Chemistry and Physics |
| بيانات النشر: |
Wiley-VCH Verlag GmbH & Co. KGaA |
| سنة النشر: |
2014 |
| المجموعة: |
Queensland University of Technology: QUT ePrints |
| مصطلحات موضوعية: |
Construction chemicals, Decomposition temperature, Empirical estimations, Esterification, Esters, Fuel additives, Glass, Industrial polymers, Knowledge based systems, Oil fields, Onset decomposition temperatures, Polymer blends, Polymers, Structure property relationships, Thermal characteristics, Thermodynamic properties, decomposition temperatures, glass transition, melting point, polyacrylates, polymethacrylates |
| الوصف: |
The glass-transition-, melting, and onset decomposition temperatures of a series of tailored polymethacrylates and polyacrylates are systematically investigated. Application fields of the investigated polymers include coatings, adhesives, textile, paper, cosmetics, electronics, lubricants, fuel additives, and oil-field or construction chemicals. The present study focuses on linear alkyl, branched alkyl, and amino, as well as ether polymethacrylates and polyacrylates. Novel polymers are introduced with branched C9, C13, C17, and C21 ester, Lupragen, or glycopyranoside ester groups. The thermal characteristics of the novel polymers are analyzed and placed into the context of the thermal data of known polymers fitting into the homologous series. General trends providing a comprehensive and concise overview of the determined thermal properties are derived. Structure-property relationships are established and a detailed physicochemical rationale is provided. The study may even allow for a rapid empirical estimation of thermal data of not yet assessed polymer systems. The thermal properties of a wide series of polyacrylates and polymethacrylates (among them completely novel structures) are systematically investigated for the first time. General trends are derived and structure-property relationships are established. The study provides a knowledge base, for industrial polymer applications, for a rapid empirical estimation of thermal polymer data, or for the tailored design of novel materials. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| Relation: |
https://www.scopus.com/inward/record.uri?eid=2-s2.0-84902439871&partnerID=40&md5=cbe8d8e622b23f46b6708a65b9a22c1b; Fleischhaker, Friederike, Haehnel, Alexander, Misske, Andrea, Blanchot, Mathieu, Haremza, Sylke, & Barner-Kowollik, Christopher (2014) Glass-transition-, melting-, and decomposition temperatures of tailored polyacrylates and polymethacrylates: General trends and structure-property relationships. Macromolecular Chemistry and Physics, 215(12), pp. 1192-1200.; https://eprints.qut.edu.au/99381/; Institute for Future Environments; Science & Engineering Faculty |
| الاتاحة: |
https://eprints.qut.edu.au/99381/ |
| Rights: |
Consult author(s) regarding copyright matters ; This work is covered by copyright. Unless the document is being made available under a Creative Commons Licence, you must assume that re-use is limited to personal use and that permission from the copyright owner must be obtained for all other uses. If the document is available under a Creative Commons License (or other specified license) then refer to the Licence for details of permitted re-use. It is a condition of access that users recognise and abide by the legal requirements associated with these rights. If you believe that this work infringes copyright please provide details by email to qut.copyright@qut.edu.au |
| رقم الانضمام: |
edsbas.8A05D177 |
| قاعدة البيانات: |
BASE |