Academic Journal
Interaction of elemental mercury with selenium surfaces: model experiments for investigations of superheavy elements copernicium and flerovium
| العنوان: | Interaction of elemental mercury with selenium surfaces: model experiments for investigations of superheavy elements copernicium and flerovium |
|---|---|
| المؤلفون: | Chiera, N. M., Aksenov, N. V., Albin, Y. V., Bozhikov, G. A., Chepigin, V. I., Dmitriev, S. N., Dressler, R., Eichler, Robert, Lebedev, V. Ya., Madumarov, A., Malyshev, O. N., Piguet, D., Popov, Y. A., Sabelnikov, A. V., Steinegger, Patrick, Svirikhin, A. I., Türler, Andreas, Vostokin, G. K., Vögele, A., Yeremin, A. V. |
| المصدر: | Chiera, N. M.; Aksenov, N. V.; Albin, Y. V.; Bozhikov, G. A.; Chepigin, V. I.; Dmitriev, S. N.; Dressler, R.; Eichler, Robert; Lebedev, V. Ya.; Madumarov, A.; Malyshev, O. N.; Piguet, D.; Popov, Y. A.; Sabelnikov, A. V.; Steinegger, Patrick; Svirikhin, A. I.; Türler, Andreas; Vostokin, G. K.; Vögele, A. and Yeremin, A. V. (2017). Interaction of elemental mercury with selenium surfaces: model experiments for investigations of superheavy elements copernicium and flerovium. Journal of Radioanalytical and Nuclear Chemistry, 311(1), pp. 99-108. Springer 10.1007/s10967-016-5018-8 |
| بيانات النشر: | Springer |
| سنة النشر: | 2017 |
| المجموعة: | BORIS (Bern Open Repository and Information System, University of Bern) |
| مصطلحات موضوعية: | 570 Life sciences, biology, 540 Chemistry |
| الوصف: | The adsorption behavior of 197Hg and 183–185Hg on red amorphous selenium (red a-Se) and trigonal selenium (t-Se) was investigated experimentally by off-line and on-line gas chromatographic methods, in preparation of a sensitive chemical separation and characterization of the transactinides copernicium (Cn, Z = 112) and flerovium (Fl, Z = 114). Monte-Carlo simulations of a diffusion controlled deposition were in good agreement with the experimental results, assuming as interaction limits −ΔHadsred a-Se(Hg) > 85 kJ/mol, and −ΔHadst-Se(Hg) < 60 kJ/mol. Both Se allotropes can be used as stationary surfaces in comparative gas-chromatographic chemical investigations of Cn and Fl. |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | application/pdf |
| اللغة: | English |
| Relation: | https://boris.unibe.ch/93784/ |
| الاتاحة: | https://boris.unibe.ch/93784/1/art%253A10.1007%252Fs10967-016-5018-8.pdf https://boris.unibe.ch/93784/ |
| Rights: | info:eu-repo/semantics/openAccess |
| رقم الانضمام: | edsbas.8945502D |
| قاعدة البيانات: | BASE |
| الوصف غير متاح. |