Academic Journal
Chirality‐Driven Self‐Assembly of Discrete, Homochiral Fe II 2 L 3 Cages
| العنوان: | Chirality‐Driven Self‐Assembly of Discrete, Homochiral Fe II 2 L 3 Cages |
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| المؤلفون: | Sun, Bin, Meeus, Eva J., de Zwart, Felix J., Bobylev, Eduard O., Mooibroek, Tiddo J., Mathew, Simon, Reek, Joost N. H. |
| المصدر: | Chemistry – A European Journal ; volume 29, issue 23 ; ISSN 0947-6539 1521-3765 |
| بيانات النشر: | Wiley |
| سنة النشر: | 2023 |
| المجموعة: | Wiley Online Library (Open Access Articles via Crossref) |
| الوصف: | Coordination chemistry is a powerful method to synthesize supramolecular cages with distinct features that suit specific applications. This work demonstrates the synthesis of discrete, homochiral Fe II 2 L 3 cages via chirality‐driven self‐assembly. Specifically, the installation of chirality – at both the vertices and ligand backbones – allows the formation of discrete, homochiral Fe II 2 L 3 cages of different sizes via stereochemical control of the iron(II) centers. We observed that larger cages require multiple chiral centra (chiral ligands and vertices). In contrast, the formation of smaller cages is stereoselective with solely chiral ligands. The latter cages can also be formed from two chiral subcomponents, but only when they have matching chirality. Single‐crystal X‐ray diffraction of these smaller Fe II 2 L 3 cages revealed several non‐covalent interactions as a driving force for narcissistic chiral self‐sorting. This expected behavior was confirmed utilizing the shorter ligands in racemic form, yielding discrete, homochiral Fe II 2 L 3 cages formed in enantiomeric pairs. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| DOI: | 10.1002/chem.202203900 |
| الاتاحة: | http://dx.doi.org/10.1002/chem.202203900 https://onlinelibrary.wiley.com/doi/pdf/10.1002/chem.202203900 https://onlinelibrary.wiley.com/doi/full-xml/10.1002/chem.202203900 |
| Rights: | http://creativecommons.org/licenses/by-nc/4.0/ |
| رقم الانضمام: | edsbas.879764FE |
| قاعدة البيانات: | BASE |
| DOI: | 10.1002/chem.202203900 |
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