Synthesis and structural characterization of a new cadmium complex with cytosine

التفاصيل البيبلوغرافية
العنوان:	Synthesis and structural characterization of a new cadmium complex with cytosine
المؤلفون:	Bancu, L., Bouroş, P.N., Bourosh, P., Боурош, П.Н., Jitaru, I., Simonov, I.A., Simonov, Y., Симонов, Ю.А., Lipkowski, J.
المصدر:	Revue Roumaine de Chimie 397-401
سنة النشر:	2006
مصطلحات موضوعية:	Cadmium complexes, Cytosine cation, Hydrogen bonds, Tautomeric forms, X-ray diffraction
الوصف:	A new cytosine cadmiumII bromide compound was prepared and characterized by electrical conductivity measurements, UV and FT-IR spectra and X-ray structural analysis. The compound is monoclinic, space group C2/c, a = 7.3551, b = 15.0511, c = 24.2661 Å, ß= 90.891deg;, V = 2685.94 Å3, Z = 4, Dcnbsp;= 2.177 g/cm3. The crystal structure is rather unusual and it is formed by two crystallographic independent cytosine cations, [CytH]+nbsp;and one [CdBr4]-nbsp;anion. The cations of cytosine are hydrogen bounded to Br anions in an arrangement allowing both inter-base stacking interactions and base pairing via hydrogen bonds.
نوع الوثيقة:	article in journal/newspaper
وصف الملف:	application/pdf
اللغة:	English
تدمد:	00353930
Relation:	https://ibn.idsi.md/vizualizare_articol/186489; urn:issn:00353930
الاتاحة:	https://ibn.idsi.md/vizualizare_articol/186489
Rights:	info:eu-repo/semantics/openAccess
رقم الانضمام:	edsbas.87565EB7
قاعدة البيانات:	BASE

الوصف
تدمد:	00353930