Academic Journal
A copper(I) coordination polymer with 3-cyanopyridine ligands
| العنوان: | A copper(I) coordination polymer with 3-cyanopyridine ligands |
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| المؤلفون: | Deng, Cui-Er, Zhu, Yu-Shu, Zhang, Xue-Chun, Tao, Yan-Lin, Liu, Xi |
| المصدر: | Zeitschrift für Naturforschung B ; volume 78, issue 7-8, page 435-439 ; ISSN 0932-0776 1865-7117 |
| بيانات النشر: | Walter de Gruyter GmbH |
| سنة النشر: | 2023 |
| الوصف: | A coordination polymer Cu(3-CP) 3 (NO 3 ) ( 1 ) was synthesized from copper(II) sulfate and 3-cyanopyridine (3-CP) with in-situ reduction by hydroxylamine sulfate via the solvent evaporation method at room temperature, and structurally characterized by single-crystal X-ray diffraction and elemental analysis. Complex 1 exhibits a structure formed by cationic [Cu(3-CP) 3 ] n n + chains and NO 3 − anions with abundant supramolecular interactions. Solid-state photoluminescence experiments show that complex 1 exhibits a relatively strong blue-green emission, and its possible emission mechanism was investigated in detail based on theoretical calculations. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| DOI: | 10.1515/znb-2023-0004 |
| DOI: | 10.1515/znb-2023-0004/xml |
| DOI: | 10.1515/znb-2023-0004/pdf |
| الاتاحة: | http://dx.doi.org/10.1515/znb-2023-0004 https://www.degruyter.com/document/doi/10.1515/znb-2023-0004/xml https://www.degruyter.com/document/doi/10.1515/znb-2023-0004/pdf |
| رقم الانضمام: | edsbas.84C76F8F |
| قاعدة البيانات: | BASE |
| DOI: | 10.1515/znb-2023-0004 |
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