التفاصيل البيبلوغرافية
| العنوان: |
Simultaneously Enhance the Heat Storage Capacity and Shape Stability of Poly(hexadecyl acrylate) by Immobilizing It to Cellulose Nanocrystal via In Situ Free Radical Polymerization |
| المؤلفون: |
Mengya Mu (11133068), Junwen Huang (8748063), Yuxiang Chen (1396720), Yingzhan Li (4024793), Hou-Yong Yu (1825279), Juming Yao (2592523) |
| سنة النشر: |
2022 |
| المجموعة: |
Smithsonian Institution: Digital Repository |
| مصطلحات موضوعية: |
Biophysics, Biochemistry, Medicine, Biotechnology, Chemical Sciences not elsewhere classified, heat storage capacity, free radical polymerization, differential scanning calorimeter, outstanding thermal reliability, good form stability, cellulose nanocrystal via, high melting enthalpy, cellulose nanocrystal, thermal properties, shape stability, tga ), supporting materials, situ <, simultaneously enhance, significantly higher, reactive vinyl, reactive site, pure hda, intermolecular forces, hexadecyl acrylate, g ), dsc ), discernible change, crystallization enthalpies, cooling cycles |
| الوصف: |
Although it was possible to produce solid–solid phase change materials (SSPCM) by loading phase change materials (PCMs) on supporting materials, the enthalpy of PCMs was always reduced. To address this issue, poly(hexadecyl acrylate) (PHDA) was immobilized to cellulose nanocrystal (CNC) through grafting and intermolecular forces, which held good crystallization promotion performance via in situ free radical polymerization. CNC was grafted with reactive vinyl, which functioned as a reactive site for polymerizing PHDA. The chemical structure, morphology, and thermal properties of CNC before and after modification were characterized with Fourier transformation infrared spectroscope (FT-IR), scanning electron microscope (SEM), thermogravimetric analyzer (TGA), and differential scanning calorimeter (DSC). The prepared SSPCM was found to have good form stability and a high melting enthalpy (139.7 J/g), which was significantly higher than pure HDA. After 100 heating and cooling cycles, there was no discernible change in the melting and crystallization enthalpies of the SSPCM, implying that it had outstanding thermal reliability and shape stability. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| Relation: |
https://figshare.com/articles/journal_contribution/Simultaneously_Enhance_the_Heat_Storage_Capacity_and_Shape_Stability_of_Poly_hexadecyl_acrylate_by_Immobilizing_It_to_Cellulose_Nanocrystal_via_i_In_Situ_i_Free_Radical_Polymerization/19099936 |
| DOI: |
10.1021/acsapm.1c01395.s001 |
| الاتاحة: |
https://doi.org/10.1021/acsapm.1c01395.s001 |
| Rights: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.840F2717 |
| قاعدة البيانات: |
BASE |