High-Temperature Behavior, Oxygen Transport Properties, and Electrochemical Performance of Cu-Substituted Nd1.6Ca0.4NiO4+δ Electrode Materials

التفاصيل البيبلوغرافية
العنوان:	High-Temperature Behavior, Oxygen Transport Properties, and Electrochemical Performance of Cu-Substituted Nd1.6Ca0.4NiO4+δ Electrode Materials
المؤلفون:	Maksimchuk, T., Filonova, E., Mishchenko, D., Eremeev, N., Sadovskaya, E., Bobrikov, I., Fetisov, A., Pikalova, N., Kolchugin, A., Shmakov, A., Sadykov, V., Pikalova, E.
المصدر:	Applied Sciences (Switzerland)
بيانات النشر:	MDPI
سنة النشر:	2022
المجموعة:	Ural Federal University (URFU): ELAR / Уральский федеральный университет: электронный архив УрФУ
مصطلحات موضوعية:	CRYSTAL STRUCTURE, ELECTRODE MATERIAL, ELECTRODE PERFORMANCE, IMPEDANCE SPECTROSCOPY, ISOTOPE EXCHANGE, NEUTRON DIFFRACTION, OXYGEN DIFFUSION, OXYGEN-ION CONDUCTOR, PROTON CONDUCTOR, SOFC
الوصف:	In this study, Nd1.6Ca0.4Ni1−yCuyO4+δ-based electrode materials for intermediate temperature solid oxide fuel cells (IT-SOFCs) are investigated. Materials of the series (y = 0–0.4) are obtained by pyrolysis of glycerol-nitrate compositions. The study of crystal structure and high-temperature stability in air and under low oxygen partial pressure atmospheres are performed using high-resolution neutron and in situ X-ray powder diffraction. All the samples under the study assume a structure with Bmab sp.gr. below 350◦C and with I4/mmm sp.gr. above 500◦C. A transition in the volume thermal expansion coefficient values from 7.8–9.3 to 9.1–12.0 × 10−6, K−1 is observed at approximately 400◦C in air and 500◦C in helium.The oxygen self-diffusion coefficient values, obtained using isotope exchange, monotonically decrease with the Cu content increasing, while concentration dependence of the charge carriers goes through the maximum at x = 0.2. The Nd1.6Ca0.4Ni0.8Cu0.2O4+δ electrode materialdemonstrates chemical compatibility and superior electrochemical performance in the symmetrical cells with Ce0.8Sm0.2O1.9, BaCe0.8Sm0.2O3−δ, BaCe0.8Gd0.19Cu0.1O3−δ and BaCe0.5Zr0.3Y0.1Yb0.1O3−δ solid electrolytes, potentially for application in IT-SOFCs. © 2022 by the authors. Licensee MDPI, Basel, Switzerland. ; 122013100200-2; Ministry of Education and Science of the Russian Federation, Minobrnauka: AAAA-A21-121011390009-1; Ural Branch, Russian Academy of Sciences, UB RAS: 122020100324-3 ; Material synthesis, sample preparation, and electrochemical studies were performed in the framework of budget tasks for the Institute of High Temperature Electrochemistry, UB RAS, project № 122020100324-3. The standard characterization of powder and ceramic materials was carried out at the Shared Access Centre “Composition of Compounds” of the Institute of High Temperature Electrochemistry, UB RAS. The synchrotron XRD experiments were performed at the shared research center SSTRC on the basis of the Novosibirsk VEPP-3 complex at BINP SB RAS. The in ...
نوع الوثيقة:	article in journal/newspaper
وصف الملف:	application/pdf
اللغة:	English
ردمك:	978-0-00-786882-7 0-00-786882-0
تدمد:	20763417
Relation:	High-Temperature Behavior, Oxygen Transport Properties, and Electrochemical Performance of Cu-Substituted Nd1.6Ca0.4NiO4+δ Electrode Materials / T. Maksimchuk, E. Filonova, D. Mishchenko et al. // Applied Sciences (Switzerland). — 2022. — Vol. 12. — Iss. 8. — 3747.; https://www.scopus.com/inward/record.uri?eid=2-s2.0-85128453184&doi=10.3390%2fapp12083747&partnerID=40&md5=8a12abf7c678f6287adef83e2d7ff342; http://elar.urfu.ru/handle/10995/117832; 85128453184; 000786882000001
DOI:	10.3390/app12083747
الاتاحة:	http://elar.urfu.ru/handle/10995/117832 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85128453184&doi=10.3390%2fapp12083747&partnerID=40&md5=8a12abf7c678f6287adef83e2d7ff342 https://doi.org/10.3390/app12083747
Rights:	info:eu-repo/semantics/openAccess
رقم الانضمام:	edsbas.81E170A8
قاعدة البيانات:	BASE

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ردمك:	9780007868827 0007868820
تدمد:	20763417
DOI:	10.3390/app12083747