Academic Journal

PVP-coated iron nanocrystals: Anhydrous synthesis, characterization, and electrocatalysis for two species

التفاصيل البيبلوغرافية
العنوان: PVP-coated iron nanocrystals: Anhydrous synthesis, characterization, and electrocatalysis for two species
المؤلفون: Guo, Lin, Huang, Qunjian, Li, Xiao-Yuan, Yang, Shihe
سنة النشر: 2006
المجموعة: The Hong Kong University of Science and Technology: HKUST Institutional Repository
مصطلحات موضوعية: Catalysis, Electrochemistry, Electrodes, Hydrogen Peroxide: chemistry, Iron: chemistry, Metal Nanoparticles: chemistry, Metal Nanoparticles: ultrastructure, Microscopy, Electron, Transmission, Nitric Oxide: chemistry, Oxidation-Reduction, Polymers: chemistry, Povidone: analogs & derivatives, Povidone: chemistry, Spectrum Analysis, Water: chemistry, X-Ray Diffraction
الوصف: We report the synthesis of Fe nanocrystals (similar to 9 nm) in an anhydrous media, formamide, using poly(N-vinyl-2pyrrolidone) (PVP) as a protecting agent. The morphology, structure, and composition of the PVP-coated Fe nanocrystals are studied by transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and FT-Raman spectroscopy. The surface properties of the PVP-coated Fe nanocrystals are studied by electrochemistry and micro-surface- enhanced Raman scattering (mSERS) using pyridine as a probing molecule. The PVP-coated Fe nanocrystals, when immobilized on an electrode substrate, display very good electrocatalytic activities in the selective reduction of H2O2 in the presence of oxygen and in the oxidation of NO.
نوع الوثيقة: article in journal/newspaper
اللغة: English
تدمد: 0743-7463
Relation: http://repository.ust.hk/ir/Record/1783.1-30676; Langmuir, v. 22, (18), 2006, Aug, p. 7867-7872; https://doi.org/10.1021/la060975i; http://lbdiscover.ust.hk/uresolver?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rfr_id=info:sid/HKUST:SPI&rft.genre=article&rft.issn=0743-7463&rft.volume=22&rft.issue=18&rft.date=2006&rft.spage=7867&rft.epage=7872&rft.aulast=Guo&rft.aufirst=Lin&rft.atitle=PVP-coated+iron+nanocrystals:+Anhydrous+synthesis,+characterization,+and+electrocatalysis+for+two+species; http://gateway.isiknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=LinksAMR&SrcApp=PARTNER_APP&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000239921800059; http://www.scopus.com/record/display.url?eid=2-s2.0-33748576244&origin=inward
DOI: 10.1021/la060975i
الاتاحة: http://repository.ust.hk/ir/Record/1783.1-30676
https://doi.org/10.1021/la060975i
http://lbdiscover.ust.hk/uresolver?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rfr_id=info:sid/HKUST:SPI&rft.genre=article&rft.issn=0743-7463&rft.volume=22&rft.issue=18&rft.date=2006&rft.spage=7867&rft.epage=7872&rft.aulast=Guo&rft.aufirst=Lin&rft.atitle=PVP-coated+iron+nanocrystals:+Anhydrous+synthesis,+characterization,+and+electrocatalysis+for+two+species
http://gateway.isiknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=LinksAMR&SrcApp=PARTNER_APP&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000239921800059
http://www.scopus.com/record/display.url?eid=2-s2.0-33748576244&origin=inward
رقم الانضمام: edsbas.7D893CDF
قاعدة البيانات: BASE
الوصف
تدمد:07437463
DOI:10.1021/la060975i